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タイトル: | Recent Progress in the Development of Solid-State Luminescent o-Carboranes with Stimuli Responsivity |
著者: | Ochi, Junki ![]() ![]() ![]() Tanaka, Kazuo ![]() ![]() ![]() Chujo, Yoshiki |
著者名の別形: | 越智, 純毅 田中, 一生 中條, 善樹 |
キーワード: | carboranes chromism emission luminescence stimuli responsivity |
発行日: | 15-Jun-2020 |
出版者: | Wiley |
誌名: | Angewandte Chemie International Edition |
巻: | 59 |
号: | 25 |
開始ページ: | 9841 |
終了ページ: | 9855 |
抄録: | o ‐Carborane, a cluster compound containing boron and adjacent carbon atoms, displays intriguing luminescent properties. Recently, compounds containing o ‐carborane units were found to show suppressed aggregation‐induced quenching and intense solid‐state emission; they also show potential for the development of stimuli‐responsive luminochromic materials. In this Minireview, we introduce three kinds of fundamental photochemical properties: aggregation‐induced emission, twisted intramolecular charge transfer in crystals, and environment‐sensitive excimer formation in solids. Based on these properties, several types of luminochromism, such as thermos‐, vapo‐, and mechanochromism, have been discovered. Based mainly on results from recent studies, we illustrate these mechanisms as well as unique luminescent behaviors of o ‐carborane derivatives. |
著作権等: | This is the peer reviewed version of the following article: J. Ochi, K. Tanaka, Y. Chujo, Angew. Chem. Int. Ed. 2020 , 59 , 9841., which has been published in final form at https://doi.org/10.1002/anie.201916666. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. The full-text file will be made open to the public on 1 April 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/252364 |
DOI(出版社版): | 10.1002/anie.201916666 |
PubMed ID: | 32009291 |
出現コレクション: | 学術雑誌掲載論文等 |
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