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このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| jacs.0c04598.pdf | 2.38 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Park, Soyeong | en |
| dc.contributor.author | Jeong, Jaeyoung | en |
| dc.contributor.author | Fujita, Ken-ichi | en |
| dc.contributor.author | Yamamoto, Akira | en |
| dc.contributor.author | Yoshida, Hisao | en |
| dc.contributor.alternative | 朴, 素暎 | ja |
| dc.contributor.alternative | 丁, 在瑛 | ja |
| dc.contributor.alternative | 藤田, 健一 | ja |
| dc.contributor.alternative | 山本, 旭 | ja |
| dc.contributor.alternative | 吉田, 寿雄 | ja |
| dc.date.accessioned | 2020-08-04T07:34:52Z | - |
| dc.date.available | 2020-08-04T07:34:52Z | - |
| dc.date.issued | 2020-07-22 | - |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.issn | 1520-5126 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/253574 | - |
| dc.description | 光触媒による第一級アミンの新合成ルートを確立 --アンモニア水を窒素源とする直接合成法の開発--. 京都大学プレスリリース. 2020-07-10. | ja |
| dc.description.abstract | A completely new route was established to synthesize valuable primary amines from alkenes by using aqueous ammonia, that is, a simple photocatalytic hydroamination of alkenes using aqueous ammonia with a metal-loaded TiO2 photocatalyst. Although the photochemical hydroamination prefers to form amines according to the Markovnikov rule, the new photocatalytic hydroamination gives anti-Markovnikov products predominantly. With an Au-loaded TiO2 photocatalyst, the amine yield reached up to 93% and the regioselectivity of anti-Markovnikov products was above 98%. The reaction mechanism was proposed for the new photocatalytic hydroamination. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Journal of the American Chemical Society', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c04598. | en |
| dc.rights | The full-text file will be made open to the public on 22 June 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving' | en |
| dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
| dc.rights | This is not the published version. Please cite only the published version. | en |
| dc.subject | Colloid and Surface Chemistry | en |
| dc.subject | Biochemistry | en |
| dc.subject | General Chemistry | en |
| dc.subject | Catalysis | en |
| dc.title | Anti-Markovnikov Hydroamination of Alkenes with Aqueous Ammonia by Metal-Loaded Titanium Oxide Photocatalyst | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Journal of the American Chemical Society | en |
| dc.identifier.volume | 142 | - |
| dc.identifier.issue | 29 | - |
| dc.identifier.spage | 12708 | - |
| dc.identifier.epage | 12714 | - |
| dc.relation.doi | 10.1021/jacs.0c04598 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 32568530 | - |
| dc.relation.url | https://www.kyoto-u.ac.jp/ja/research-news/2020-07-10-0 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2021-06-22 | - |
| datacite.awardNumber | 19K15359 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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