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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.202004476.pdf | 824.26 kB | Adobe PDF | 見る/開く |
| タイトル: | Stereoselective Synthesis of 1,1′-Disaccharides by Organoboron Catalysis |
| 著者: | Izumi, Sanae Kobayashi, Yusuke Takemoto, Yoshiji    https://orcid.org/0000-0003-1375-3821 (unconfirmed) |
| 著者名の別形: | 小林, 祐輔 竹本, 佳司 |
| キーワード: | carbohydrates glycosylation organocatalysis total synthesis trehalose |
| 発行日: | 10-Aug-2020 |
| 出版者: | Wiley |
| 誌名: | Angewandte Chemie |
| 巻: | 59 |
| 号: | 33 |
| 開始ページ: | 14054 |
| 終了ページ: | 14059 |
| 抄録: | The highly stereoselective synthesis of 1, 1′‐disaccharides was achieved by using 1, 2‐dihydroxyglycosyl acceptors and glycosyl donors in the presence of a tricyclic borinic acid catalyst. In this reaction, the complexation of the diols and the catalyst is crucial for the activation of glycosyl donors, as well as for the 1, 2‐cis‐configuration of the products. The anomeric stereochemistry of the glycosyl donor depends on the employed glycosyl donor. Applications of the produced 1, 1′‐disaccharides are also described. |
| 著作権等: | This is the peer reviewed version of the following article: S. Izumi, Y. Kobayashi, Y. Takemoto, Angew. Chem. Int. Ed. 2020, 59, 14054, which has been published in final form at https://doi.org/10.1002/anie.202004476. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. The full-text file will be made open to the public on 4 June 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/254663 |
| DOI(出版社版): | 10.1002/anie.202004476 |
| PubMed ID: | 32385890 |
| 関連リンク: | https://doi.org/10.1002/ange.202004476 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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