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タイトル: | Short positron lifetime at vacancies observed in electron-irradiated tungsten: Experiments and first-principles calculations |
著者: | Yabuuchi, A. Tanaka, M. Kinomura, A. |
著者名の別形: | 籔内, 敦 木野村, 淳 |
キーワード: | Tungsten Electron-irradiation Vacancy-impurity complex Dissociation energy Positron annihilation lifetime spectroscopy First-principles calculation |
発行日: | 15-Dec-2020 |
出版者: | Elsevier BV |
誌名: | Journal of Nuclear Materials |
巻: | 542 |
論文番号: | 152473 |
抄録: | A positron lifetime component of ~170 ps has been reported for irradiated tungsten (W) in some studies. This value is considerably shorter than that calculated for isolated monovacancies (~200 ps). In this study, positron annihilation lifetime spectroscopy was used to investigate the recovery behavior of the defects with a short positron lifetime of ~170 ps in electron-irradiated W. The binding energies and positron lifetimes of vacancy-impurity complexes decorated with impurity atoms were calculated. A positron lifetime of 169 ps, which was similar to the experimentally observed lifetime of 171 ± 1 ps, was calculated for defect complexes comprising a monovacancy decorated with two hydrogen atoms (V-2H complexes). In addition, a value of 1.42 eV was calculated for the dissociation energy of a hydrogen atom from the V-H and V-2H complexes, and the defects with a positron lifetime of ~170 ps were experimentally observed to migrate at 623 K. These were consistent with previously reported dissociation energy and desorption temperature of deuterium from vacancies in W studied by thermal desorption spectroscopy. These results suggested that the vacancies observed in the electron-irradiated W were hydrogen-decorated V-nH complexes. |
著作権等: | © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. The full-text file will be made open to the public on 15 December 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/254702 |
DOI(出版社版): | 10.1016/j.jnucmat.2020.152473 |
出現コレクション: | 学術雑誌掲載論文等 |
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