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dc.contributor.authorOgawa, Naokien
dc.contributor.authorYamaoka, Yousukeen
dc.contributor.authorTakikawa, Hiroshien
dc.contributor.authorYamada, Ken-ichien
dc.contributor.authorTakasu, Kiyoseien
dc.contributor.alternative小川, 直希ja
dc.contributor.alternative山岡, 庸介ja
dc.contributor.alternative瀧川, 紘ja
dc.contributor.alternative山田, 健一ja
dc.contributor.alternative高須, 清誠ja
dc.date.accessioned2020-10-02T00:35:57Z-
dc.date.available2020-10-02T00:35:57Z-
dc.date.issued2020-08-05-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/2433/255251-
dc.descriptionうねり構造をもつグラフェンナノリボンの精密合成に成功 --非ベンゼノイド構造の新規構築反応を開発--. 京都大学プレスリリース. 2020-07-20.ja
dc.description.abstractThe azulene moiety, composed of contiguous pentagonal and heptagonal rings, is a structural defect that alters the electronic, magnetic, and structural properties of graphenes and graphene nanoribbons. However, nanographenes embedded with an azulene cluster have not been widely investigated because these compounds are difficult to synthesize in their pure form. Herein, azulene-embedded nanographenes bearing a unique cove-type edge were synthesized by a novel synthetic protocol. Experimental and theoretical investigations revealed that this cove edge imparts stable helical chirality, unlike normal cove edges. The in-solution self-association behavior and the structural, electronic, and electrochemical properties were also described in detail.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society (ACS)en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c06156.en
dc.rightsThe full-text file will be made open to the public on 17 July 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.titleHelical Nanographenes Embedded with Contiguous Azulene Unitsen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleJournal of the American Chemical Societyen
dc.identifier.volume142-
dc.identifier.issue31-
dc.identifier.spage13322-
dc.identifier.epage13327-
dc.relation.doi10.1021/jacs.0c06156-
dc.textversionauthor-
dc.identifier.pmid32677830-
dc.relation.urlhttp://www.kyoto-u.ac.jp/ja/research/research_results/2020/200717_1.html-
dcterms.accessRightsopen access-
datacite.date.available2021-07-17-
datacite.awardNumber19K22185-
datacite.awardNumber19H03350-
datacite.awardNumber18H04406-
datacite.awardNumber19J14061-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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