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dc.contributor.authorKinoshita, Junen
dc.contributor.authorBaralle, Alexandreen
dc.contributor.authorYoshida, Akiraen
dc.contributor.authorYanagi, Tomoyukien
dc.contributor.authorNogi, Keisukeen
dc.contributor.authorYorimitsu, Hidekien
dc.contributor.alternative木下, 純ja
dc.contributor.alternative吉田, 陽ja
dc.contributor.alternative柳, 智征ja
dc.contributor.alternative野木, 馨介ja
dc.contributor.alternative依光, 英樹ja
dc.date.accessioned2020-10-30T05:44:37Z-
dc.date.available2020-10-30T05:44:37Z-
dc.date.issued2020-10-
dc.identifier.issn2193-5807-
dc.identifier.urihttp://hdl.handle.net/2433/255852-
dc.description.abstractAn S−N variant of the N−N‐based Fischer indole synthesis has been developed. Treatment of sulfonanilides and ketene dithioacetal monoxides with a powerful acid anhydride provides N‐sulfonyl‐2‐methylsulfanylindoles. The initial interrupted Pummerer reaction would yield the key S−N‐tethered precursor in situ that then undergoes [3, 3] sigmatropic rearrangement, after which the endgame to the indole ring follows the Fischer manner.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherWiley-VCH Verlagen
dc.rightsThis is the peer reviewed version of the following article: J. Kinoshita, A. Baralle, A. Yoshida, T. Yanagi, K. Nogi, H. Yorimitsu, Asian J. Org. Chem. 2020, 9, 1655, which has been published in final form at https://doi.org/10.1002/ajoc.202000397. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en
dc.rightsThe full-text file will be made open to the public on 1 September 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.subjectindolesen
dc.subjectalkenyl sulfoxidesen
dc.subjectanilinesen
dc.subjectsigmatropic rearrangementen
dc.subjectinterrupted Pummerer reactionen
dc.titleA Route to Indoles via Modified Fischer Indole Intermediates from Sulfonanilides and Ketene Dithioacetal Monoxidesen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleAsian Journal of Organic Chemistryen
dc.identifier.volume9-
dc.identifier.issue10-
dc.identifier.spage1655-
dc.identifier.epage1659-
dc.relation.doi10.1002/ajoc.202000397-
dc.textversionauthor-
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dcterms.accessRightsopen access-
datacite.date.available2021-09-01-
datacite.awardNumberJP18H04254-
datacite.awardNumberJP18H04409-
datacite.awardNumberJP19H00895-
datacite.awardNumberJP18K14212-
datacite.awardNumberJP20K1527-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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