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dc.contributor.authorOkamoto, Koichien
dc.contributor.authorNogi, Keisukeen
dc.contributor.authorShimokawa, Junen
dc.contributor.authorYorimitsu, Hidekien
dc.contributor.alternative岡本, 浩一ja
dc.contributor.alternative野木, 馨介ja
dc.contributor.alternative下川, 淳ja
dc.contributor.alternative依光, 英樹ja
dc.date.accessioned2020-10-30T06:45:11Z-
dc.date.available2020-10-30T06:45:11Z-
dc.date.issued2020-05-04-
dc.identifier.issn0947-6539-
dc.identifier.issn1521-3765-
dc.identifier.urihttp://hdl.handle.net/2433/255854-
dc.description.abstractSelective C−F arylation of polyfluorophenols with aryl sulfoxides has been accomplished by means of a sigmatropic dearomatization/defluorination sequence. This sequence consists of three processes: 1) interrupted Pummerer reaction to form S−O‐tethered sulfonium salt; 2) C−C‐forming [3, 3] sigmatropic rearrangement with dearomatization; and 3) Zn‐mediated defluorinative rearomatization. The present biaryl construction provides a facile access to polyfluorinated biaryls that is difficult to synthesize by other methods. The synthetic utility of the strategy is clearly demonstrated by the synthesis of a fluorinated analogue of Maxipost, a potassium channel modulator.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherWileyen
dc.rightsThis is the peer reviewed version of the following article: K. Okamoto, K. Nogi, J. Shimokawa, H. Yorimitsu, Chem. Eur. J. 2020, 26, 5615, which has been published in final form at https://doi.org/10.1002/chem.202001158. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en
dc.rightsThe full-text file will be made open to the public on 15 April 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.subjectbiarylsen
dc.subjectC−F transformationen
dc.subjectinterrupted Pummerer reactionen
dc.subjectsigmatropic rearrangementen
dc.subjectsynthetic methodsen
dc.titleC−F Arylation of Polyfluorophenols by Means of Sigmatropic Dearomatization/Defluorination Sequenceen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleChemistry - A European Journalen
dc.identifier.volume26-
dc.identifier.spage5615-
dc.identifier.epage5618-
dc.relation.doi10.1002/chem.202001158-
dc.textversionauthor-
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.identifier.pmid32149436-
dcterms.accessRightsopen access-
datacite.date.available2021-04-15-
datacite.awardNumberJP16H04109-
datacite.awardNumberJP18H04254-
datacite.awardNumberJP18H04409-
datacite.awardNumberJP19H00895-
datacite.awardNumberJP18K14212-
dc.identifier.pissn0947-6539-
dc.identifier.eissn1521-3765-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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