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j.electacta.2020.136289.pdf4.28 MBAdobe PDF見る/開く
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dc.contributor.authorZhang, Zeleien
dc.contributor.authorKitada, Atsushien
dc.contributor.authorFukami, Kazuhiroen
dc.contributor.authorYao, Zhengjunen
dc.contributor.authorMurase, Kuniakien
dc.contributor.alternative張, 澤磊ja
dc.contributor.alternative北田, 敦ja
dc.contributor.alternative深見, 一弘ja
dc.contributor.alternative邑瀬, 邦明ja
dc.date.accessioned2020-11-02T02:13:45Z-
dc.date.available2020-11-02T02:13:45Z-
dc.date.issued2020-07-10-
dc.identifier.issn0013-4686-
dc.identifier.issn1873-3859-
dc.identifier.urihttp://hdl.handle.net/2433/255858-
dc.description.abstractElectrodeposition of iron (Fe) from an ethereal solution was investigated. The bath consisted of ferrous chloride (FeCl₂), diglyme (G2), and aluminum chloride (AlCl₃), in which iron species were estimated to be [Fe(G2)₂]²⁺ complex cations. The effect of hydrogen gas evolution on the morphology of iron deposits was determined by comparing common aqueous electrolytes. An Fe thin film was fabricated using the FeCl₂–G2–AlCl₃ bath without the influence of hydrogen gas evolution, and the nucleation of Fe was explained by an instantaneous nucleation mechanism. As a result, the surface morphology of the Fe thin film was compact and smooth compared with the cases of aqueous and other nonaqueous electrolytes.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier BVen
dc.rights© 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectIron electrodepositionen
dc.subjectSurface morphologyen
dc.subjectThin filmen
dc.subjectNucleation mechanismen
dc.subjectEthereal electrolyteen
dc.titleElectrodeposition of an iron thin film with compact and smooth morphology using an ethereal electrolyteen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleElectrochimica Actaen
dc.identifier.volume348-
dc.relation.doi10.1016/j.electacta.2020.136289-
dc.textversionpublisher-
dc.identifier.artnum136289-
dc.addressCollege of Material Science and Technology, Nanjing University of Aeronautics and Astronautics・Department of Materials Science and Engineering, Kyoto Universityen
dc.addressDepartment of Materials Science and Engineering, Kyoto Universityen
dc.addressDepartment of Materials Science and Engineering, Kyoto Universityen
dc.addressCollege of Material Science and Technology, Nanjing University of Aeronautics and Astronauticsen
dc.addressDepartment of Materials Science and Engineering, Kyoto Universityen
dcterms.accessRightsopen access-
datacite.awardNumber19H02490-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
出現コレクション:学術雑誌掲載論文等

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