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dc.contributor.authorIto, Shiorien
dc.contributor.authorFukazawa, Mizukien
dc.contributor.authorTakahashi, Fumiyaen
dc.contributor.authorNogi, Keisukeen
dc.contributor.authorYorimitsu, Hidekien
dc.contributor.alternative伊藤, 詩織ja
dc.contributor.alternative深澤, 瑞喜ja
dc.contributor.alternative高橋, 郁也ja
dc.contributor.alternative野木, 馨介ja
dc.contributor.alternative依光, 英樹ja
dc.date.accessioned2020-11-10T08:18:54Z-
dc.date.available2020-11-10T08:18:54Z-
dc.date.issued2020-10-
dc.identifier.issn0009-2673-
dc.identifier.issn1348-0634-
dc.identifier.urihttp://hdl.handle.net/2433/255899-
dc.description.abstractReductive 1, 2-diboration of alkynes has been accomplished by means of sodium dispersion in the presence of trimethoxyborane as a reduction-resistant boron electrophile. Two boron moieties can be introduced onto alkynes with excellent syn selectivity to afford the corresponding (Z)-1, 2-diborylalkenes. Bis(borate) species generated in situ can be involved in one-pot Suzuki-Miyaura arylation, formal arylboration of alkynes thus being executed.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherChemical Society of Japanen
dc.rights© 2020 The Chemical Society of Japanen
dc.rights発行元の許可を得て掲載しています。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.subject1, 2-Diborationen
dc.subjectAlkyneen
dc.subjectSodium metalen
dc.titleSodium-metal-promoted reductive 1,2-syn-diboration of alkynes with reduction-resistant trimethoxyboraneen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleBulletin of the Chemical Society of Japanen
dc.identifier.volume93-
dc.identifier.issue10-
dc.identifier.spage1171-
dc.identifier.epage1179-
dc.relation.doi10.1246/BCSJ.20200110-
dc.textversionauthor-
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dcterms.accessRightsopen access-
datacite.awardNumberJP16H04109-
datacite.awardNumberJP18H04254-
datacite.awardNumberJP18H04409-
datacite.awardNumberJP19H00895-
datacite.awardNumberJP18K14212-
datacite.awardNumberJP20K15275-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
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