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dc.contributor.authorYamada, Kodaien
dc.contributor.authorYanagi, Tomoyukien
dc.contributor.authorYorimitsu, Hidekien
dc.contributor.alternative山田, 航大ja
dc.contributor.alternative柳, 智征ja
dc.contributor.alternative依光, 英樹ja
dc.date.accessioned2021-01-15T06:13:42Z-
dc.date.available2021-01-15T06:13:42Z-
dc.date.issued2020-12-18-
dc.identifier.issn1523-7060-
dc.identifier.issn1523-7052-
dc.identifier.urihttp://hdl.handle.net/2433/261022-
dc.description.abstractReadily available aryldimethylsulfonium triflates react with zinc powder under nickel catalysis via the selective cleavage of the sp2-hybridized carbon–sulfur bond to produce salt-free arylzinc triflates under mild conditions. This zincation displays superb chemoselectivity and thus represents a protocol that is complementary or orthogonal to existing methods. The generated arylzinc reagents show both high reactivity and chemoselectivity in palladium-catalyzed and copper-mediated cross-coupling reactions.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Societyen
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c03782.en
dc.rightsThe full-text file will be made open to the public on 10 December 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.titleGeneration of Organozinc Reagents from Arylsulfonium Salts Using a Nickel Catalyst and Zinc Dusten
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleOrganic Lettersen
dc.identifier.volume22-
dc.identifier.issue24-
dc.identifier.spage9712-
dc.identifier.epage9718-
dc.relation.doi10.1021/acs.orglett.0c03782-
dc.textversionauthor-
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDepartment of Chemistry, Graduate School of Science, Kyoto Universityen
dc.identifier.pmid33300805-
dcterms.accessRightsopen access-
datacite.date.available2021-11-10-
datacite.awardNumberJP19H00895-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
出現コレクション:学術雑誌掲載論文等

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