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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| s-0040-1706538.pdf | 664.7 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Wang, Shuo | - |
| dc.contributor.author | Kaga, Atsushi | - |
| dc.contributor.author | Yorimitsu, Hideki | - |
| dc.contributor.alternative | 王, 爍 | - |
| dc.contributor.alternative | 加賀, 敦志 | - |
| dc.contributor.alternative | 依光, 英樹 | - |
| dc.date.accessioned | 2021-02-16T04:24:30Z | - |
| dc.date.available | 2021-02-16T04:24:30Z | - |
| dc.date.issued | 2021-01 | - |
| dc.identifier.issn | 0936-5214 | - |
| dc.identifier.issn | 1437-2096 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/261698 | - |
| dc.description.abstract | Sodium dispersion promotes reductive ring opening of arylcyclopropanes. The presence of a reduction-resistant electrophile, such as methoxypinacolatoborane, epoxide, oxetane, paraformaldehyde, or chlorotrimethylsilane, during the reductive ring opening event leads to the formation of 1, 3-difunctionalized 1-arylalkanes by immediate trappings of the resulting two reactive carbanions. In particular, the ring-opening 1, 3-diborylations of arylcyclopropanes afford 1, 3-diborylalkanes with high syn selectivity. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Georg Thieme Verlag | - |
| dc.rights | This is the accepted manuscript of the article, which has been published at https://doi.org/10.1055/s-0040-1706538. | - |
| dc.rights | The full-text file will be made open to the public on 22 October 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | - |
| dc.rights | This is not the published version. Please cite only the published version. | en |
| dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
| dc.subject | carbanions | - |
| dc.subject | cleavage | - |
| dc.subject | diastereoselectivity | - |
| dc.subject | electron transfer | - |
| dc.subject | metalation | - |
| dc.subject | reduction | - |
| dc.subject | ring opening | - |
| dc.subject | sodium | - |
| dc.title | Reductive Ring-Opening 1,3-Difunctionalizations of Arylcyclopropanes with Sodium Metal | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Synlett | en |
| dc.identifier.volume | 32 | - |
| dc.identifier.issue | 2 | - |
| dc.identifier.spage | 219 | - |
| dc.identifier.epage | 223 | - |
| dc.relation.doi | 10.1055/s-0040-1706538 | - |
| dc.textversion | author | - |
| dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | - |
| dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | - |
| dc.address | Department of Chemistry, Graduate School of Science, Kyoto University | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2021-10-22 | - |
| datacite.awardNumber | JP19H00895 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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