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dc.contributor.author | Gu, Yifan | en |
dc.contributor.author | Zheng, Jia‐Jia | en |
dc.contributor.author | Otake, Ken‐ichi | en |
dc.contributor.author | Sugimoto, Kunihisa | en |
dc.contributor.author | Hosono, Nobuhiko | en |
dc.contributor.author | Sakaki, Shigeyoshi | en |
dc.contributor.author | Li, Fengting | en |
dc.contributor.author | Kitagawa, Susumu | en |
dc.contributor.alternative | 大竹, 研一 | ja |
dc.contributor.alternative | 杉本, 邦久 | ja |
dc.contributor.alternative | 細野, 暢彦 | ja |
dc.contributor.alternative | 榊, 茂好 | ja |
dc.contributor.alternative | 北川, 進 | ja |
dc.date.accessioned | 2021-03-23T07:09:19Z | - |
dc.date.available | 2021-03-23T07:09:19Z | - |
dc.date.issued | 2020-09-01 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2433/262262 | - |
dc.description | German version: https://doi.org/10.1002/ange.202003186 | - |
dc.description.abstract | To achieve unique molecular‐recognition patterns, a rational control of the flexibility of porous coordination polymers (PCPs) is highly sought, but it remains elusive. From a thermodynamic perspective, the competitive relationship between the structural deformation energy (Edef) of soft PCPs and the guest interaction is key for selective a guest‐triggered structural‐transformation behavior. Therefore, it is vital to investigate and control Edef to regulate this competition for flexibility control. Driven by these theoretical insights, we demonstrate an Edef‐modulation strategy via encoding inter‐framework hydrogen bonds into a soft PCP with an interpenetrated structure. As a proof of this concept, the enhanced Edef of PCP enables a selective gate‐opening behavior toward CHCl₃ over CH₂Cl₂ by changing the adsorption‐energy landscape of the compounds. This study provides a new direction for the design of functional soft porous materials. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley | en |
dc.rights | This is the peer reviewed version of the following article: Y. Gu, J.-J. Zheng, K.-i. Otake, K. Sugimoto, N. Hosono, S. Sakaki, F. Li, S. Kitagawa, Angew. Chem. Int. Ed. 2020, 59, 15517, which has been published in final form at https://doi.org/10.1002/anie.202003186. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | en |
dc.rights | The full-text file will be made open to the public on 4 May 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.subject | energy landscape | en |
dc.subject | flexibility | en |
dc.subject | molecular recognition | en |
dc.subject | porous coordination polymer | en |
dc.subject | structural-deformation energy | en |
dc.title | Structural‐Deformation‐Energy‐Modulation Strategy in a Soft Porous Coordination Polymer with an Interpenetrated Framework | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Angewandte Chemie International Edition | en |
dc.identifier.volume | 59 | - |
dc.identifier.issue | 36 | - |
dc.identifier.spage | 15517 | - |
dc.identifier.epage | 15521 | - |
dc.relation.doi | 10.1002/anie.202003186 | - |
dc.textversion | author | - |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University・College of Environmental Science and Engineering, Shanghai Institute of Pollution Control and Ecological Security, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University | en |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University・Fukui Institute for Fundamental Chemistry, Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University | en |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University | en |
dc.address | Fukui Institute for Fundamental Chemistry, Kyoto University | en |
dc.address | College of Environmental Science and Engineering, Shanghai Institute of Pollution Control and Ecological Security, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University | en |
dc.address | Institute for Integrated Cell-Material Sciences, Kyoto University Institute for Advanced Study, Kyoto University | en |
dc.identifier.kaken | JP19H05381 / JP25000007 / JP18H05262 / JP19K15584 / JP18H02072 | - |
dc.relation.url | https://doi.org/10.1002/ange.202003186 | - |
dcterms.accessRights | open access | - |
datacite.date.available | 2021-05-04 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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