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dc.contributor.authorKinouchi, Hayateen
dc.contributor.authorSugimoto, Kazumaen
dc.contributor.authorYamaoka, Yousukeen
dc.contributor.authorTakikawa, Hiroshien
dc.contributor.authorTakasu, Kiyoseien
dc.contributor.alternative紀之内, 颯ja
dc.contributor.alternative杉本, 和馬ja
dc.contributor.alternative山岡, 庸介ja
dc.contributor.alternative瀧川, 紘ja
dc.contributor.alternative高須, 清誠ja
dc.date.accessioned2021-12-08T06:43:37Z-
dc.date.available2021-12-08T06:43:37Z-
dc.date.issued2021-09-17-
dc.identifier.urihttp://hdl.handle.net/2433/266490-
dc.description.abstractTreatment of aryl-fused bicyclo[4.2.0]octanols with an oxidant such as phenyliodine diacetate (PIDA) or hypochlorous acid gave dihydrofuran-containing polycyclic aromatic compounds by selective β-cleavage of the cyclobutanol moiety. Mechanistic studies suggest that the oxygen atom of the hydrofuran ring is incorporated from the hydroxy group of the substrate via intramolecular addition. The oxidative transformation should serve as a new method to prepare functionalized polycyclic aromatic compounds.en
dc.language.isoeng-
dc.publisherAmerican Chemical Society (ACS)en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in 'The Journal of Organic Chemistry', copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.1c01108.en
dc.rightsThe full-text file will be made open to the public on 2 September 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。en
dc.titleOxidative β-Cleavage of Fused Cyclobutanols Leading to Hydrofuran-Fused Polycyclic Aromatic Compoundsen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.ncidAA00704100-
dc.identifier.jtitleThe Journal of Organic Chemistryen
dc.identifier.volume86-
dc.identifier.issue18-
dc.identifier.spage12615-
dc.identifier.epage12622-
dc.relation.doi10.1021/acs.joc.1c01108-
dc.textversionauthor-
dc.identifier.pmid34474562-
dcterms.accessRightsopen access-
datacite.date.available2022-09-02-
datacite.awardNumber19H03350-
datacite.awardNumber19K22185-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19H03350/-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-19K22185/-
dc.identifier.pissn0022-3263-
dc.identifier.eissn1520-6904-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.awardTitle小員環および中員環のひずみを活用した生物機能性分子の設計と評価ja
jpcoar.awardTitle分極構造をもつアズレン縮環グラフェンナノリボンの合成と物性評価ja
出現コレクション:学術雑誌掲載論文等

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