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タイトル: | Control of Proton‐Conductive Behavior with Nanoenvironment within Metal–Organic Materials |
著者: | Otake, Ken‐ichi Kitagawa, Hiroshi ![]() ![]() ![]() |
著者名の別形: | 大竹, 研一 北川, 宏 |
キーワード: | crystalline porous materials, crystal structures metal–organic materials nanoconfinement effect porous coordination polymers proton conductivities |
発行日: | Jun-2021 |
出版者: | Wiley |
誌名: | Small |
巻: | 17 |
号: | 22 |
論文番号: | 2006189 |
抄録: | Solid-state proton-conductive materials have been of great interest for several decades due to their promising application as electrolytes in fuel cells and electrochemical devices. Metal-organic materials (MOMs) have recently been intensively investigated as a new type of proton-conductive materials. The highly crystalline nature and structural designability of MOMs make them advantageous over conventional noncrystalline proton-conductive materials-the detailed investigation of the structure-property relationship is feasible on MOM-based proton conductors. This review aims to summarize and examine the fundamental principles and various design strategies on proton-conductive MOMs, and shed light on the nanoconfinement effects as well as the importance of hydrophobicity on specific occasions, which have been often disregarded. Besides, challenges and future prospects on this field are presented. |
著作権等: | This is the peer reviewed version of the following article: [Otake, K., Kitagawa, H., Control of Proton-Conductive Behavior with Nanoenvironment within Metal–Organic Materials. Small 2021, 17, 2006189.], which has been published in final form at https://doi.org/10.1002/smll.202006189. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. The full-text file will be made open to the public on 18 March 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/268729 |
DOI(出版社版): | 10.1002/smll.202006189 |
PubMed ID: | 33733595 |
出現コレクション: | 学術雑誌掲載論文等 |

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