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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| chem.202005223.pdf | 1.57 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Kaga, Atsushi | en |
| dc.contributor.author | Iida, Hirokazu | en |
| dc.contributor.author | Tsuchiya, Shun | en |
| dc.contributor.author | Saito, Hayate | en |
| dc.contributor.author | Nakano, Koji | en |
| dc.contributor.author | Yorimitsu, Hideki | en |
| dc.contributor.alternative | 加賀, 敦志 | ja |
| dc.contributor.alternative | 土屋, 駿 | ja |
| dc.contributor.alternative | 齊藤, 颯 | ja |
| dc.contributor.alternative | 依光, 英樹 | ja |
| dc.date.accessioned | 2022-03-10T09:06:57Z | - |
| dc.date.available | 2022-03-10T09:06:57Z | - |
| dc.date.issued | 2021-03 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/268764 | - |
| dc.description.abstract | A new mode of aromatic metamorphosis has been developed, which allows thiophenes and their benzo-fused derivatives to be converted to a variety of exotic heteroles. This transformation involves 1) the efficient generation of key 1, 4-dianions by means of desulfurative dilithiation with lithium powder and 2) the subsequent trapping of the dianions with heteroatom electrophiles in a one-pot manner. Via the desulfurative dilithiation, the sulfur atoms of thiophenes are replaced also with a carbon–carbon double bond or a 1, 2-phenylene for the construction of benzene rings. | en |
| dc.language.iso | eng | - |
| dc.publisher | Wiley | en |
| dc.rights | This is the peer reviewed version of the following article: [A. Kaga, H. Iida, S. Tsuchiya, H. Saito, K. Nakano, H. Yorimitsu, Chem. Eur. J. 2021, 27, 4567.], which has been published in final form at https://doi.org/10.1002/chem.202005223. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | en |
| dc.rights | The full-text file will be made open to the public on 05 February 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | desulfurization | en |
| dc.subject | dianion | en |
| dc.subject | heterole | en |
| dc.subject | lithium metal | en |
| dc.subject | thiophene | en |
| dc.title | Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Chemistry – A European Journal | en |
| dc.identifier.volume | 27 | - |
| dc.identifier.issue | 14 | - |
| dc.identifier.spage | 4567 | - |
| dc.identifier.epage | 4572 | - |
| dc.relation.doi | 10.1002/chem.202005223 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 33349986 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2022-02-05 | - |
| datacite.awardNumber | 18H04254 | - |
| datacite.awardNumber | 18H04409 | - |
| datacite.awardNumber | 19H00895 | - |
| datacite.awardNumber | 18J22838 | - |
| datacite.awardNumber | 20J01639 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-18H04254/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-18H04409/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19H00895/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18J22838/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20J01639/ | - |
| dc.identifier.pissn | 0947-6539 | - |
| dc.identifier.eissn | 1521-3765 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | アート錯体の精密制御によるヘテロ芳香環の開環と原子挿入 | ja |
| jpcoar.awardTitle | フロー系が可能にするプメラー型ビアリール構築による中分子合成 | ja |
| jpcoar.awardTitle | 芳香環の還元的破壊に基づく有機合成 | ja |
| jpcoar.awardTitle | 遷移金属触媒を用いたボラサイクルの新規合成法の開発 | ja |
| jpcoar.awardTitle | 金属リチウムの強還元能を鍵としたヘテロπ共役系骨格の構築 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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