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dc.contributor.author | Gon, Masayuki | en |
dc.contributor.author | Wakabayashi, Junko | en |
dc.contributor.author | Nakamura, Masashi | en |
dc.contributor.author | Tanaka, Kazuo | en |
dc.contributor.author | Chujo, Yoshiki | en |
dc.contributor.alternative | 権, 正行 | ja |
dc.contributor.alternative | 若林, 純子 | ja |
dc.contributor.alternative | 中村, 将志 | ja |
dc.contributor.alternative | 田中, 一生 | ja |
dc.contributor.alternative | 中條, 善樹 | ja |
dc.date.accessioned | 2022-05-06T05:22:43Z | - |
dc.date.available | 2022-05-06T05:22:43Z | - |
dc.date.issued | 2021-04 | - |
dc.identifier.uri | http://hdl.handle.net/2433/269616 | - |
dc.description.abstract | Most organic luminescent dyes usually show poor emission in solid due to aggregation-caused quenching due to nonspecific intermolecular interaction, such as π–π stacking. Furthermore, since commodity molecules having near-infrared (NIR) emission properties tend to have extended π-conjugated systems, development of luminescent organic materials with solid-state NIR emission has been still challenging. Herein, the series of the azobenzene complexes with the perpendicularly-protruded aryl derivative at the boron atom toward π-conjugated system is synthesized. From the optical measurements, it is shown that these complexes can show crystallization-induced emission enhancement behaviors. The donor–acceptor type π-conjugated polymers composed of the azobenzene complexes are also synthesized. Highly-efficient NIR emission from the phenyl-substituted polymers both in solution (λ[PL] = 742 nm, Φ[PL] = 15%) and film states (λ[PL] = 793 nm, Φ[PL] = 9%) is obtained. Furthermore, emission wavelengths can be tuned by changing the substituent at the boron atom to the modified aryl groups. From mechanistic studies including theoretical calculations, it is shown that electronic interaction is allowable between the aryl substituent to the π-conjugated system through the tetradentate boron. | en |
dc.language.iso | eng | - |
dc.publisher | Wiley | en |
dc.rights | This is the peer reviewed version of the following article: [Gon, M., Wakabayashi, J., Nakamura, M., Tanaka, K., Chujo, Y., Preparation of Near-Infrared Emissive π-Conjugated Polymer Films Based on Boron-Fused Azobenzene Complexes with Perpendicularly Protruded Aryl Substituents. Macromol. Rapid Commun. 2021, 42, 2000566.], which has been published in final form at https://doi.org/10.1002/marc.202000566. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | en |
dc.rights | The full-text file will be made open to the public on 30 November 2021 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
dc.subject | azobenzene | en |
dc.subject | boron | en |
dc.subject | conjugated polymers | en |
dc.subject | NIR | en |
dc.subject | solid-state emission | en |
dc.title | Preparation of Near-Infrared Emissive π-Conjugated Polymer Films Based on Boron-Fused Azobenzene Complexes with Perpendicularly Protruded Aryl Substituents | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Macromolecular Rapid Communications | en |
dc.identifier.volume | 42 | - |
dc.identifier.issue | 8 | - |
dc.relation.doi | 10.1002/marc.202000566 | - |
dc.textversion | author | - |
dc.identifier.artnum | 2000566 | - |
dc.identifier.pmid | 33251636 | - |
dcterms.accessRights | open access | - |
datacite.date.available | 2021-11-30 | - |
datacite.awardNumber | 20K15334 | - |
datacite.awardNumber | 17H03067 | - |
datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K15334/ | - |
datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H03067/ | - |
dc.identifier.pissn | 1022-1336 | - |
dc.identifier.eissn | 1521-3927 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.awardTitle | 超原子価を含む典型元素配位構造を利用した機能性共役系高分子の創出 | ja |
jpcoar.awardTitle | 13族元素の高周期化による新奇光機能性高分子の創出 | ja |
出現コレクション: | 学術雑誌掲載論文等 |
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