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tcr.202100202.pdf | 809.72 kB | Adobe PDF | 見る/開く |
タイトル: | Azido‐Alkynes in Gold(I)‐Catalyzed Indole Syntheses |
著者: | Greiner, Luca C. Matsuoka, Junpei Inuki, Shinsuke https://orcid.org/0000-0002-7525-1280 (unconfirmed) Ohno, Hiroaki https://orcid.org/0000-0002-3246-4809 (unconfirmed) |
著者名の別形: | 松岡, 純平 井貫, 晋輔 大野, 浩章 |
キーワード: | gold(I)-carbenes gold-catalysis heterocycles natural product synthesis medium-sized rings |
発行日: | Dec-2021 |
出版者: | Wiley |
誌名: | The Chemical Record |
巻: | 21 |
号: | 12 |
開始ページ: | 3897 |
終了ページ: | 3910 |
抄録: | The exploitation of nitrogen-functionalized reactive intermediates plays an important role in the synthesis of biologically relevant scaffolds in the field of pharmaceutical sciences. Those based on gold carbenes carry a strong potential for the design of highly efficient cascade processes toward the synthesis of compounds containing a fused indole core structure. This personal account gives a detailed explanation of our contribution to this sector, and embraces the reaction development of efficient gold-catalyzed cascade processes based on diversely functionalized azido-alkynes. Challenging cyclizations and their subsequent application in the synthesis of pharmaceutically relevant scaffolds and natural products conducted in an intra- or intermolecular fashion are key features of our research. |
著作権等: | This is the peer reviewed version of the following article: ['The Chemical Record', Volume21, Issue12, Special Issue: Recent Advances in Transition‐Metal Catalysis, December 2021, Pages 3897-3910], which has been published in final form at https://doi.org/10.1002/tcr.202100202. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. The full-text file will be made open to the public on 08 September 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/274131 |
DOI(出版社版): | 10.1002/tcr.202100202 |
PubMed ID: | 34498385 |
出現コレクション: | 学術雑誌掲載論文等 |
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