このアイテムのアクセス数: 137
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acsomega.1c05739.pdf | 1.7 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Hashikawa, Yoshifumi | en |
| dc.contributor.author | Murata, Yasujiro | en |
| dc.contributor.alternative | 橋川, 祥史 | ja |
| dc.contributor.alternative | 村田, 靖次郎 | ja |
| dc.date.accessioned | 2022-06-30T04:18:55Z | - |
| dc.date.available | 2022-06-30T04:18:55Z | - |
| dc.date.issued | 2021-12 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/274619 | - |
| dc.description.abstract | We showcase efficient synthetic protocols of cyclopentadienyl metal dicarbonyl, CpM(CO)₂ (M = Rh and Ir). Reflecting the relativistic effect, the ¹H and ¹³C signals of the Cp ring in CpIr(CO)₂ were upfield shifted when compared with the Rh analogue. A missing dinuclear complex, (CpIr)₂(μ-CO)(CO)₂, was spontaneously generated together with [CpIr(CO)]₃ by the loss of CO. The crystallographic analyses unambiguously determined their unique structures with one and three Ir–Ir bonds, respectively. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | Copyright © 2021 The Authors. Published by American Chemical Society | en |
| dc.rights | This is an open access article published under a Creative Commons Non-Commercial NoDerivative Works Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. | en |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
| dc.subject | Lipids | en |
| dc.subject | Metals | en |
| dc.subject | Crystal structure | en |
| dc.subject | Oligomers | en |
| dc.subject | Transition metals | en |
| dc.title | Synthesis and Oligomerization of CpM(CO)₂ | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | ACS Omega | en |
| dc.identifier.volume | 6 | - |
| dc.identifier.issue | 49 | - |
| dc.identifier.spage | 34137 | - |
| dc.identifier.epage | 34141 | - |
| dc.relation.doi | 10.1021/acsomega.1c05739 | - |
| dc.textversion | publisher | - |
| dc.identifier.pmid | 34926961 | - |
| dcterms.accessRights | open access | - |
| datacite.awardNumber | 17H06119 | - |
| datacite.awardNumber | 20K15260 | - |
| datacite.awardNumber | 20H05218 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H06119/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20K15260/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-20H05218/ | - |
| dc.identifier.eissn | 2470-1343 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | ナノスケールラボラトリーの創製と深化 | ja |
| jpcoar.awardTitle | 単分子化学を指向した炭素ナノケージの創出 | ja |
| jpcoar.awardTitle | 水酸基の3次元精密配列に基づく高次集積構造の構築 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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