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dc.contributor.authorBonneau, Mickaeleen
dc.contributor.authorSugimoto, Kunihisaen
dc.contributor.authorOtake, Ken‐ichien
dc.contributor.authorTsuji, Yukikoen
dc.contributor.authorShimanaka, Nanaeen
dc.contributor.authorLavenn, Christopheen
dc.contributor.authorKitagawa, Susumuen
dc.contributor.alternative杉本, 邦久ja
dc.contributor.alternative大竹, 研一ja
dc.contributor.alternative辻, 有輝子ja
dc.contributor.alternative嶋中, 七重ja
dc.contributor.alternative北川, 進ja
dc.date.accessioned2022-08-03T07:15:47Z-
dc.date.available2022-08-03T07:15:47Z-
dc.date.issued2021-10-
dc.identifier.urihttp://hdl.handle.net/2433/275724-
dc.description.abstractPorous coordination polymers (PCPs) with pore decoration have been used as materials for excellent storage and separation functions. The cooperative properties of flexible PCPs can be utilized to achieve the separation of mixtures of gaseous molecules having highly similar properties. The key to efficient molecular recognition and separation lies in increasing the degrees of freedom of the structure without sacrificing the stability of the system. However, the mechanism study of such behavior is still scarce in the literature. Here, we focused on PCPs with two-dimensional Kagomè lattice structures and functionalized the pores with various alkoxy pendant groups; this facilitated systematic tuning of the pore aperture size, the interlayer spacing, as well as the interactions between the host and adsorbed molecules. The combination of characterization techniques allowed us to observe a unique deformation of the lattice upon gas sorption, allowing the separation of gas molecules with similar physicochemical properties, such as propane and propylene.en
dc.language.isoeng-
dc.publisherWileyen
dc.rights© 2021 The Authors. Natural Sciences published by Wiley-VCH GmbHen
dc.rightsThis is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/-
dc.subjectgas separationen
dc.subjectmetal-organic frameworken
dc.subjectporous coordination polymeren
dc.subjectsoft porous crystalen
dc.subjectstructural flexibilityen
dc.titleGuest‐selective gate‐opening by pore engineering of two‐dimensional Kagomè lattice porous coordination polymersen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleNatural Sciencesen
dc.identifier.volume1-
dc.identifier.issue2-
dc.relation.doi10.1002/ntls.10020-
dc.textversionpublisher-
dc.identifier.artnume10020-
dcterms.accessRightsopen access-
datacite.awardNumber25000007-
datacite.awardNumber18H05262-
datacite.awardNumber19K15584-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25000007/-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18H05262/-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K15584/-
dc.identifier.eissn2698-6248-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.awardTitle階層的配位空間の化学ja
jpcoar.awardTitle適応性空間の化学ja
jpcoar.awardTitleChemistry of Adaptable Spaceen
jpcoar.awardTitle金属伝導性を示す多孔性配位高分子の開発ja
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