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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.inorgchem.2c00646.pdf | 650.58 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Mukoyoshi, Megumi | en |
| dc.contributor.author | Maesato, Mitsuhiko | en |
| dc.contributor.author | Kawaguchi, Shogo | en |
| dc.contributor.author | Kubota, Yoshiki | en |
| dc.contributor.author | Cho, Keigo | en |
| dc.contributor.author | Kitagawa, Yasutaka | en |
| dc.contributor.author | Kitagawa, Hiroshi | en |
| dc.contributor.alternative | 向吉, 恵 | ja |
| dc.contributor.alternative | 前里, 光彦 | ja |
| dc.contributor.alternative | 北川, 宏 | ja |
| dc.date.accessioned | 2022-09-29T01:39:10Z | - |
| dc.date.available | 2022-09-29T01:39:10Z | - |
| dc.date.issued | 2022-05-16 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/276390 | - |
| dc.description.abstract | Recently, mixed-metal metal–organic frameworks (MOFs) have been attracting much attention in various fields. In this study, we have systematically investigated the magnetic properties of CoxNi₁–x-MOF-74 [Co₂xNi₂(₁–x)(dhtp), where H₄dhtp = 2, 5-dihydroxyterephthalic acid] with two different kinds of metals (Co and Ni) across the composition range 0 ≤ x ≤ 1. Bimetallic CoxNi₁–x-MOF-74 (x = 0.752, 0.458, and 0.233) were successfully synthesized and confirmed to have homogeneous metal distributions. Weak ferromagnetic (canted antiferromagnetic) behavior was exhibited, while homometallic Co-MOF-74 and Ni-MOF-74 are antiferromagnetic. We also investigated the effects of C₂H₄ sorption on the magnetic properties and found that C₂H₄-adsorbed Co₀.₅Ni₀.₅-MOF-74 exhibited a change in the interchain magnetic interaction. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.2c00646. | en |
| dc.rights | The full-text file will be made open to the public on 8 September 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | Diffraction | en |
| dc.subject | Ions | en |
| dc.subject | Magnetic properties | en |
| dc.subject | Metal organic frameworks | en |
| dc.subject | Metals | en |
| dc.title | Systematic Tuning of the Magnetic Properties in Mixed-Metal MOF-74 | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Inorganic Chemistry | en |
| dc.identifier.volume | 61 | - |
| dc.identifier.issue | 19 | - |
| dc.identifier.spage | 7226 | - |
| dc.identifier.epage | 7230 | - |
| dc.relation.doi | 10.1021/acs.inorgchem.2c00646 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 35506706 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2023-05-04 | - |
| datacite.awardNumber | 20H05623 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H05623/ | - |
| dc.identifier.pissn | 0020-1669 | - |
| dc.identifier.eissn | 1520-510X | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 非平衡合成による多元素ナノ合金の創製 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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