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dc.contributor.authorTakebe, Hiyorien
dc.contributor.authorMatsubara, Seijiroen
dc.contributor.alternative竹邊, 日和ja
dc.contributor.alternative松原, 誠二郎ja
dc.date.accessioned2022-10-05T06:13:05Z-
dc.date.available2022-10-05T06:13:05Z-
dc.date.issued2022-10-07-
dc.identifier.urihttp://hdl.handle.net/2433/276586-
dc.description【研究成果】正立方体型分子から六面体かご型分子へと骨格を変えることに成功. 京都大学プレスリリース. 2022-06-24.ja
dc.description.abstract2, 6-Disubstituted cuneane has potential as a p -disubstituted benzene bioisostere and a novel chiral scaffold. It is a constitutional isomer of a 1, 4-disubstituted cubane obtained via a metal-catalyzed skeletal rearrangement. Unlike the highly symmetrical 1, 4-disubstituted cubane, the isomerized 2, 6-disubstituted cuneane is a chiral molecule possessing C 2 symmetry. Examining various chiral catalysts revealed that the Pd-pincer catalyst provides a good asymmetric induction.en
dc.language.isoeng-
dc.publisherWileyen
dc.rightsThis is the peer reviewed version of the following article: [H. Takebe, S. Matsubara, Eur. J. Org. Chem. 2022, e202200567.], which has been published in final form at https://doi.org/10.1002/ejoc.202200567. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.en
dc.rightsThe full-text file will be made open to the public on 11 July 2023 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。en
dc.subjectAsymmetric Synthesis Chiral Scaffold Cuneane Cubane Pd-pinceren
dc.titleCatalytic Asymmetric Synthesis of 2,6‐Disubstituted Cuneanes via Enantioselective Constitutional Isomerization of 1,4‐Disubstituted Cubanesen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleEuropean Journal of Organic Chemistryen
dc.identifier.volume2022-
dc.identifier.issue37-
dc.relation.doi10.1002/ejoc.202200567-
dc.textversionauthor-
dc.identifier.artnume202200567-
dc.addressKyoto University Faculty of Engineering Graduate School of Engineering (Kyoto Daigaku Kogakubu Daigakuin Kogaku Kenkyuka)en
dc.addressKyoto University Faculty of Engineering Graduate School of Engineering (Kyoto Daigaku Kogakubu Daigakuin Kogaku Kenkyuka)en
dc.relation.urlhttps://www.t.kyoto-u.ac.jp/ja/news/topics/research/20220624-
dcterms.accessRightsopen access-
datacite.date.available2023-07-11-
datacite.awardNumber21H05233-
datacite.awardNumberJPMJMI20G4-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-21H05233/-
datacite.awardNumber.urihttps://projectdb.jst.go.jp/grant/JST-PROJECT-20349735/-
dc.identifier.pissn1434-193X-
dc.identifier.eissn1099-0690-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName科学技術振興機構ja
jpcoar.awardTitle2.5次元構造体のための物質創製ja
jpcoar.awardTitle簡素型AI支援有機合成システムによる有機分子工学の革新ja
出現コレクション:学術雑誌掲載論文等

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