このアイテムのアクセス数: 158
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| D1CC02154K.pdf | 1.02 MB | Adobe PDF | 見る/開く |
| タイトル: | Ni@onion-like carbon and Co@amorphous carbon: control of carbon structures by metal ion species in MOFs |
| 著者: | Mukoyoshi, Megumi    https://orcid.org/0000-0001-7672-6519 (unconfirmed)Kobayashi, Hirokazu Kusada, Kohei https://orcid.org/0000-0002-9679-6749 (unconfirmed)Otsubo, Kazuya https://orcid.org/0000-0003-4688-2822 (unconfirmed)Maesato, Mitsuhiko Kubota, Yoshiki Yamamoto, Tomokazu Matsumura, Syo Kitagawa, Hiroshi https://orcid.org/0000-0001-6955-3015 (unconfirmed) |
| 著者名の別形: | 向吉, 恵 小林, 浩和 草田, 康平 大坪, 主弥 前里, 光彦 北川, 宏 |
| 発行日: | Jun-2021 |
| 出版者: | Royal Society of Chemistry (RSC) |
| 誌名: | Chemical Communications |
| 巻: | 57 |
| 号: | 48 |
| 開始ページ: | 5897 |
| 終了ページ: | 5900 |
| 抄録: | We first report the facile synthesis of metal-carbon composites consisting of metal nanoparticles (NPs) and different types of carbon species: onion-like and amorphous carbon, Ni@onion-like carbon and Co@amorphous carbon. By simply changing the metal species in an isostructural metal-organic framework, thermal decompositions of MOF-74 directly afforded different types of metal NPs and carbon composites, which exhibited good electrical conductivity. In particular, the Ni@onion-like carbon, having a well-ordered carbon structure, had high electrical conductivity (sigma = 5.3 omega(-1) cm(-1) at 295 K), explained by a modified model of the Efros-Shklovskii variable range hopping. |
| 著作権等: | This is an accepted manuscript of this article which has been published in final form at https://doi.org/10.1039/D1CC02154K. The full-text file will be made open to the public on 15 May 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
| URI: | http://hdl.handle.net/2433/277599 |
| DOI(出版社版): | 10.1039/D1CC02154K |
| PubMed ID: | 34031675 |
| 出現コレクション: | 学術雑誌掲載論文等 |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。