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DCフィールド | 値 | 言語 |
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dc.contributor.author | FUENO, Takayuki | en |
dc.contributor.author | TAKEDA, Yoshimitsu | en |
dc.contributor.author | FURUKAWA, Junji | en |
dc.date.accessioned | 2023-03-28T09:05:57Z | - |
dc.date.available | 2023-03-28T09:05:57Z | - |
dc.date.issued | 1965-02-27 | - |
dc.identifier.uri | http://hdl.handle.net/2433/280620 | - |
dc.description.abstract | A classical inductive-effect model has been utilized in an attempt to estimate the change distribution in relatively complicated σ-bond systems. It is assumed that the formal charge on an atom is given as a vectorial sum of the polarities of the bonds attached to that atom and, further, that each bond induces a constant fraction of its own polarity in all of its neighboring bonds. Significance of the model has been tested for several model compounds which permit the closed-form solutions for the distributions of the internally self-consistent bond polarities. The model has been applied to the calculations of the charge distributions in alkanes, ォ-alkyl halides and hydrated metallic ions ; the results are found to be compatible with observations. | en |
dc.language.iso | eng | - |
dc.publisher | Faculty of Engineering, Kyoto University | en |
dc.publisher.alternative | 京都大学工学部 | ja |
dc.subject.ndc | 500 | - |
dc.title | An Attempt to Estimate the Charge Distribution in Sigma-Bond Systems | en |
dc.type | departmental bulletin paper | - |
dc.type.niitype | Departmental Bulletin Paper | - |
dc.identifier.ncid | AA00732503 | - |
dc.identifier.jtitle | Memoirs of the Faculty of Engineering, Kyoto University | en |
dc.identifier.volume | 27 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 143 | - |
dc.identifier.epage | 154 | - |
dc.textversion | publisher | - |
dc.sortkey | 11 | - |
dc.address | Department of Synthetic Chemistry | en |
dc.address | Department of Synthetic Chemistry | en |
dc.address | Department of Synthetic Chemistry | en |
dcterms.accessRights | open access | - |
dc.identifier.pissn | 0023-6063 | - |
出現コレクション: | Vol.27 Part 1 |
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