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タイトル: | Reaction Kinetics of Oxidation of Sodium Sulfite in Aqueous Solution by Rapid-Mixing Flow Method |
著者: | YASUNISHI, Akira |
発行日: | 31-Mar-1977 |
出版者: | Faculty of Engineering, Kyoto University |
誌名: | Memoirs of the Faculty of Engineering, Kyoto University |
巻: | 39 |
号: | 1 |
開始ページ: | 122 |
終了ページ: | 133 |
抄録: | The homogeneous reaction rate of oxygen and sodium sulfite in an aqueous solution catalyzed by cupric ion was investigated by the rapid-mixing flow method. The performance of the experimental apparatus was examined and proved to be suitable for the study of the kinetics of gas-liquid reactions. The rate of reaction was found to be a half order with respect to the initial concentration of oxygen, first order with respect to sulfite, and a quarter order with respect to cupric ion. But in each run, the apparent reaction rate was zero order with respect to oxygen. |
URI: | http://hdl.handle.net/2433/281024 |
出現コレクション: | Vol.39 Part 1 |
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