このアイテムのアクセス数: 35
このアイテムのファイル:
| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| acs.joc.3c02142.pdf | 543.03 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Hashimoto, Naoki | en |
| dc.contributor.author | Taguchi, Junichi | en |
| dc.contributor.author | Arichi, Norihito | en |
| dc.contributor.author | Inuki, Shinsuke | en |
| dc.contributor.author | Ohno, Hiroaki | en |
| dc.contributor.alternative | 橋本, 直季 | ja |
| dc.contributor.alternative | 田口, 淳一 | ja |
| dc.contributor.alternative | 有地, 法人 | ja |
| dc.contributor.alternative | 井貫, 晋輔 | ja |
| dc.contributor.alternative | 大野, 浩章 | ja |
| dc.date.accessioned | 2023-12-25T00:16:37Z | - |
| dc.date.available | 2023-12-25T00:16:37Z | - |
| dc.date.issued | 2023-12-15 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/286469 | - |
| dc.description.abstract | A gold-catalyzed cyclization reaction of alkynyl-indoles has been developed for the stereoselective construction of the quaternary carbon center of fused indolines. This reaction efficiently produces fused indolines via diastereoselective 6-endo-dig cyclization controlled by a bulky TIPS group, followed by nucleophilic attack of the carboxy group on the resulting imine. The lactone moiety of the fused indoline can be reductively cleaved to produce a tricyclic indoline, which could be useful for the synthesis of akuammiline alkaloids. | en |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society (ACS) | en |
| dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'The Journal of Organic Chemistry', copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.3c02142 | en |
| dc.rights | The full-text file will be made open to the public on December 5, 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | Column chromatography | en |
| dc.subject | Cyclization | en |
| dc.subject | Lipids | en |
| dc.subject | Mixtures | en |
| dc.subject | Organic compounds | en |
| dc.title | Gold(I)-Catalyzed Cascade Cyclization of Alkynyl Indoles for the Stereoselective Construction of the Quaternary Carbon Center of Akuammiline Alkaloids | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | The Journal of Organic Chemistry | en |
| dc.identifier.volume | 88 | - |
| dc.identifier.issue | 24 | - |
| dc.identifier.spage | 17306 | - |
| dc.identifier.epage | 17321 | - |
| dc.relation.doi | 10.1021/acs.joc.3c02142 | - |
| dc.textversion | author | - |
| dc.identifier.pmid | 38051730 | - |
| dcterms.accessRights | embargoed access | - |
| datacite.date.available | 2024-12-05 | - |
| datacite.awardNumber | 23H02603 | - |
| datacite.awardNumber | 22K19028 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H02603/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22K19028/ | - |
| dc.identifier.pissn | 0022-3263 | - |
| dc.identifier.eissn | 1520-6904 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 連続環化反応を基盤とする天然物合成研究と中分子モダリティへの展開 | ja |
| jpcoar.awardTitle | 独自のビニルカチオン発生法を基盤とするお椀型高度𝞹共役系分子の創製 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
このリポジトリに保管されているアイテムはすべて著作権により保護されています。