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dc.contributor.authorHanabata, Shotaen
dc.contributor.authorKusada, Koheien
dc.contributor.authorYamamoto, Tomokazuen
dc.contributor.authorToriyama, Takaakien
dc.contributor.authorMatsumura, Syoen
dc.contributor.authorKawaguchi, Shogoen
dc.contributor.authorKubota, Yoshikien
dc.contributor.authorNishida, Yoshihideen
dc.contributor.authorHaneda, Masaakien
dc.contributor.authorKitagawa, Hiroshien
dc.contributor.alternative花畑, 翔太ja
dc.contributor.alternative草田, 康平ja
dc.contributor.alternative山本, 知一ja
dc.contributor.alternative鳥山, 誉亮ja
dc.contributor.alternative松村, 晶ja
dc.contributor.alternative河口, 彰吾ja
dc.contributor.alternative久保田, 佳基ja
dc.contributor.alternative西田, 吉秀ja
dc.contributor.alternative羽田, 政明ja
dc.contributor.alternative北川, 宏ja
dc.date.accessioned2024-01-11T01:13:41Z-
dc.date.available2024-01-11T01:13:41Z-
dc.date.issued2024-01-10-
dc.identifier.urihttp://hdl.handle.net/2433/286580-
dc.description10元系多元素酸化物ナノ結晶の瞬時合成 --1秒未満で合成完了!焼成が不要な合成方法--. 京都大学プレスリリース. 2024-01-05.ja
dc.description.abstractHigh-entropy oxide nanoparticles (HEO NPs) have been intensively studied because of their attractive properties, such as high stability and enhanced catalytic activity. In this work, for the first time, denary HEO NPs were successfully synthesized using a continuous supercritical hydrothermal flow process without calcination. Interestingly, this process allows the formation of HEO NPs on the order of seconds at a relatively lower temperature. The synthesized HEO NPs contained 10 metal elements, La, Ca, Sr, Ba, Fe, Mn, Co, Ru, Pd, and Ir, and had a perovskite-type structure. Atomic-resolution high-angle annular dark-field scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy measurements revealed homogeneous dispersion of the 10 metal elements. The obtained HEO NPs also exhibited a higher catalytic activity for the CO oxidation reaction than that of the LaFeO₃ NPs.en
dc.language.isoeng-
dc.publisherAmerican Chemical Society (ACS)en
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Journal of the American Chemical Society', copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.3c07351en
dc.rightsThe full-text file will be made open to the public on December 28, 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsThis is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。en
dc.subjectAnionsen
dc.subjectCatalytic activityen
dc.subjectElementsen
dc.subjectSolution chemistryen
dc.subjectTransition metalsen
dc.titleDenary High-Entropy Oxide Nanoparticles Synthesized by a Continuous Supercritical Hydrothermal Flow Processen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleJournal of the American Chemical Societyen
dc.identifier.volume146-
dc.identifier.issue1-
dc.identifier.spage181-
dc.identifier.epage186-
dc.relation.doi10.1021/jacs.3c07351-
dc.textversionauthor-
dc.addressDivision of Chemistry, Graduate School of Science, Kyoto Universityen
dc.addressDivision of Chemistry, Graduate School of Science, Kyoto University; The HAKUBI Center for Advanced Research, Kyoto Universityen
dc.addressThe Ultramicroscopy Research Center, Kyushu Universityen
dc.addressThe Ultramicroscopy Research Center, Kyushu Universityen
dc.addressThe Ultramicroscopy Research Center, Kyushu University; Department of Applied Quantum Physics and Nuclear Engineering, Kyushu Universityen
dc.addressCenter for Synchrotron Radiation Research, Japan Synchrotron Radiation Research Institute (JASRI), SPring-8en
dc.addressDepartment of Physics, Graduate School of Science, Osaka Metropolitan Universityen
dc.addressAdvanced Ceramics Research Center, Nagoya Institute of Technologyen
dc.addressAdvanced Ceramics Research Center, Nagoya Institute of Technologyen
dc.addressDivision of Chemistry, Graduate School of Science, Kyoto Universityen
dc.identifier.pmid38153046-
dc.relation.urlhttps://www.kyoto-u.ac.jp/ja/research-news/2024-01-05-0-
dcterms.accessRightsembargoed access-
datacite.date.available2024-12-28-
datacite.awardNumber20H05623-
datacite.awardNumber21H01762-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H05623/-
datacite.awardNumber.urihttps://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21H01762/-
dc.identifier.pissn0002-7863-
dc.identifier.eissn1520-5126-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName日本学術振興会ja
jpcoar.awardTitle非平衡合成による多元素ナノ合金の創製ja
jpcoar.awardTitle多変量解析によるハイエントロピー合金(HEA)触媒の開発と超HEAナノ粒子の創製ja
出現コレクション:学術雑誌掲載論文等

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