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dc.contributor.authorOkumura, Ryosukeen
dc.contributor.authorKusakabe, Yuen
dc.contributor.authorRauch, Florianen
dc.contributor.authorLubczyk, Lukasen
dc.contributor.authorSuzuki, Katsuakien
dc.contributor.authorMarder, Todd B.en
dc.contributor.authorKaji, Hironorien
dc.contributor.alternative奥村, 亮祐ja
dc.contributor.alternative日下部, 悠ja
dc.contributor.alternative鈴木, 克明ja
dc.contributor.alternative梶, 弘典ja
dc.date.accessioned2024-11-20T06:39:51Z-
dc.date.available2024-11-20T06:39:51Z-
dc.date.issued2024-04-
dc.identifier.urihttp://hdl.handle.net/2433/290471-
dc.description.abstractEfficient reverse intersystem crossing (RISC) is an important process for thermally activated delayed fluorescence (TADF) to suppress efficiency roll-off in organic LEDs (OLEDs). Enhancing spin–orbit coupling is effective for fast RISC and is achieved by mediating a locally excited triplet state when RISC occurs between charge transfer states. Here, we experimentally confirmed that efficient RISC occurred in triarylborane-based TADF emitters named Phox-[Me]π, Phox-[MeO]π, and [MeO]3Ph-[FMe]π. The three emitters showed large RISC rate constants exceeding 10⁶ s⁻¹. The Phox-[Me]π-based OLED exhibited higher maximum external quantum efficiency (EQEₘₐₓ = 10.0%) compared to the Phox-[MeO]π-based OLED (EQEₘₐₓ = 6.7%).en
dc.language.isoeng-
dc.publisherIOP Publishingen
dc.publisherThe Japan Society of Applied Physicsen
dc.rights© 2024 The Author(s). Published on behalf of The Japan Society of Applied Physics by IOP Publishing Ltden
dc.rightsContent from this work may be used under the terms of the Creative Commons Attribution 4.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.en
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/-
dc.titleTriarylborane-based thermally activated delayed fluorescence materials with an efficient reverse intersystem crossingen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleApplied Physics Expressen
dc.identifier.volume17-
dc.identifier.issue4-
dc.relation.doi10.35848/1882-0786/ad392a-
dc.textversionpublisher-
dc.identifier.artnum041003-
dcterms.accessRightsopen access-
dc.identifier.pissn1882-0778-
dc.identifier.eissn1882-0786-
出現コレクション:学術雑誌掲載論文等

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