Discovery of collective nonjumping motions leading to Johari–Goldstein process of stress relaxation in model ionic glass

Abstract

The slow β, or Johari–Goldstein (JG) relaxation process, has been widely observed in glasses and is known to induce the stress relaxation associated with mechanical properties. So far, jumping motions of only a fraction of the particles were believed to contribute to the JG process in glass. However, there is no direct experimental evidence of the atomic-scale images due to the difficulties in microscopic observation. In this study, atomic motions in the quasi-spherical model ionic-glass-former Ca[0.4]K[0.6](NO₃)[1.4] were microscopically observed with one-angstrom resolution, the highest resolution to date, using X-ray time-domain interferometry. The microscopic experiment directly indicated that most particles underwent angstrom-scale motions in the time scale of the JG relaxation. This result was further supported by molecular dynamics (MD) simulations. A combined study of experiments and MD simulations revealed that most particles contributed to the JG process through unexpected collective nonjumping motions with angstrom-scale displacement, activated by jumping motions of a fraction of particles. The discovery of nonjumping motions by our atomic-scale dynamic observations has considerably advanced our understanding of the puzzling mechanism of the JG process.