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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.202305480.pdf | 10.4 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Huang, Long-Tao | en |
| dc.contributor.author | Kitakawa, Yuta | en |
| dc.contributor.author | Yamada, Kodai | en |
| dc.contributor.author | Kamiyama, Futa | en |
| dc.contributor.author | Kojima, Masahiro | en |
| dc.contributor.author | Yoshino, Tatsuhiko | en |
| dc.contributor.author | Matsunaga, Shigeki | en |
| dc.contributor.alternative | 吉野, 達彦 | ja |
| dc.contributor.alternative | 松永, 茂樹 | ja |
| dc.date.accessioned | 2025-05-29T02:27:09Z | - |
| dc.date.available | 2025-05-29T02:27:09Z | - |
| dc.date.issued | 2023-07-17 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/294412 | - |
| dc.description.abstract | Sulfondiimines are diaza-analogues of sulfones with a chiral sulfur center. Compared to sulfones and sulfoximines, their synthesis and transformations have so far been studied to a lesser extent. Here, we report the enantioselective synthesis of 1, 2-benzothiazine 1-imines, i.e., cyclic sulfondiimine derivatives from sulfondiimines and sulfoxonium ylides via C−H alkylation/cyclization reactions. The combination of [Ru(p-cymene)Cl₂]₂ and a newly developed chiral spiro carboxylic acid is key to achieving high enantioselectivity. | en |
| dc.language.iso | eng | - |
| dc.publisher | Wiley | en |
| dc.rights | This is the peer reviewed version of the following article: [L.-T. Huang, Y. Kitakawa, K. Yamada, F. Kamiyama, M. Kojima, T. Yoshino, S. Matsunaga, Angew. Chem. Int. Ed. 2023, 62, e202305480.], which has been published in final form at https://doi.org/10.1002/anie.202305480. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | en |
| dc.rights | The full-text file will be made open to the public on 06 June 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
| dc.rights | This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | en |
| dc.subject | 1, 2-Benzothiazine 1-Imine | en |
| dc.subject | Asymmetric Catalysis | en |
| dc.subject | C−H Activation | en |
| dc.subject | Ruthenium | en |
| dc.subject | Sulfondiimine | en |
| dc.title | Enantioselective Synthesis of 1,2-Benzothiazine 1-Imines via Ru[II]/Chiral Carboxylic Acid-Catalyzed C−H Alkylation/Cyclization | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Angewandte Chemie International Edition | en |
| dc.identifier.volume | 62 | - |
| dc.identifier.issue | 29 | - |
| dc.relation.doi | 10.1002/anie.202305480 | - |
| dc.textversion | author | - |
| dc.identifier.artnum | e202305480 | - |
| dc.identifier.pmid | 37194697 | - |
| dcterms.accessRights | open access | - |
| datacite.date.available | 2024-06-06 | - |
| datacite.awardNumber | 20H02730 | - |
| datacite.awardNumber | 23H00293 | - |
| datacite.awardNumber | 21K05046 | - |
| datacite.awardNumber | 22H05327 | - |
| datacite.awardNumber | 21A204 | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H02730/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23H00293/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05046/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-22H05327/ | - |
| datacite.awardNumber.uri | https://kaken.nii.ac.jp/grant/KAKENHI-AREA-21A204/ | - |
| dc.identifier.pissn | 1433-7851 | - |
| dc.identifier.eissn | 1521-3773 | - |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.funderName | 日本学術振興会 | ja |
| jpcoar.awardTitle | 第９族金属触媒-キラル酸ハイブリッドの精密化による不斉C-H官能基化の深化と拡張 | ja |
| jpcoar.awardTitle | キラル２核金属触媒の２金属間協働機能に基づく遠隔位C-H結合の不斉官能基化 | ja |
| jpcoar.awardTitle | キラル2-ピリドン誘導体と第9族金属による不斉C(sp3)-H官能基化 | ja |
| jpcoar.awardTitle | 量子化学計算と機械学習の組み合わせによる不斉C-H官能基化触媒の深化 | ja |
| jpcoar.awardTitle | デジタル化による高度精密有機合成の新展開 | ja |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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