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dc.contributor.authorKusuhara, Sigeruja
dc.contributor.transcriptionクスハラ, シゲルja
dc.date.accessioned2007-09-10T06:43:22Z-
dc.date.available2007-09-10T06:43:22Z-
dc.date.issued1960-08ja
dc.identifier.issn0034-6675ja
dc.identifier.urihttp://hdl.handle.net/2433/46787-
dc.description.abstractThe explosion limits of propylene mixed with oxygen or air are determined at reduced pressures and at high pressures (up to 15kg/cm^2) by the admission method. By the same method, those of acrolein mixed with oxygen or air are determined at reduced pressures. As to the propylene mixed with oxygen, the minimum explosion temperatures at any constant reduced pressures are shown by mixtures of 30~40% of propylene, but at high pressures by those of 30~70% of propylene. On the mixtures of propylene or acrolein rich in oxygen or air, the explosion peninsulas are observed at reduced pressures. The induction periods are measured and it is found that the periods inside the explosion peninsula are much longer than those outside the peninsula. As to the mixture of propylene (50%) mixed with oxygen, the cool flame regions are determined. The addition of nitrogen makes the explosion much weaker and it would be considered to affect the process of the propagation. The apparent activation energies of the reactions are estimated from the explosion limits according to Semenov's theory and from the relationship between the logarithum of the induction period and the reciprocal of the absolute temperature.ja
dc.language.isoengja
dc.publisherThe Physico-Chemical Society of Japanja
dc.titleStudies on the explosions of propylene and acrolein mixed with oxygen or airja
dc.type.niitypeDepartmental Bulletin Paperja
dc.identifier.ncidAA00817661ja
dc.identifier.jtitleThe Review of Physical Chemistry of Japanja
dc.identifier.volume30ja
dc.identifier.issue1ja
dc.identifier.spage34ja
dc.identifier.epage44ja
dc.textversionpublisherja
dc.sortkey005ja
Appears in Collections:Vol.30 No.1

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