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Title: The effect of pressure on the rate of the benzidine rearrangement
Authors: Osugi, Jiro
Hitouji, Tetsuo
Issue Date: 20-Jun-1965
Publisher: The Physico-Chemical Society of Japan
Journal title: The Review of Physical Chemistry of Japan
Volume: 34
Issue: 2
Start page: 88
End page: 96
Abstract: The rate of the acid-catalysed rearrangement of hydrazobenzene in aqueous ethanol (95 wt.% EtOH) has been measured at pressures up to 5, 000 atmospheres. The reaction is slightly slowed by high pressures and the proportion of benzidine is increased, but not to so high degree. The results indicate that the rearrangement goes through a cyclic transition state, in which at least two partial bonds are predominant.
URI: http://hdl.handle.net/2433/46853
Appears in Collections:Vol.34 No.2

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