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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| rpcjpnv35p083.pdf | 1.38 MB | Adobe PDF | 見る/開く |
| タイトル: | Studies on the telomerization of ethylene with carbon tetrachloride : I. Kinetics of the telomerization initiated by azo-bis-isobutyronitrile |
| 著者: | Kitamura, Kiyoshi |
| 著者名の別形: | キタムラ, キヨシ |
| 発行日: | 30-Apr-1966 |
| 出版者: | The Physico-Chemical Society of Japan |
| 誌名: | The Review of Physical Chemistry of Japan |
| 巻: | 35 |
| 号: | 2 |
| 開始ページ: | 83 |
| 終了ページ: | 91 |
| 抄録: | The telomerization of ethylene with carbon tetrachloride initiated by AIBN (azo-bis-isobutyronilrile) has been investigated kinetically. Reactions were carried out continuously in a tubular coil reactor at temperatures between 85° and 100℃ at constant pressure of 150kg/cm^2. It has been shown that the reaction rate of ethylene follows the rate equation : -d[C_2H_4]/dt/=k'[C_2H_4][AIBN]^1/2. Chain transfer constants of the telomer radicals to carbon tetrachloride were calculated as follows: C_1=0.1, C_2=2.1, C_3=3.8 and C_4=5.2. |
| URI: | http://hdl.handle.net/2433/46868 |
| 出現コレクション: | Vol.35 No.2 |
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