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dc.contributor.authorKubota, Hironobuja
dc.contributor.transcriptionクボタ, ヒロノブja
dc.date.accessioned2007-09-10T06:45:33Z-
dc.date.available2007-09-10T06:45:33Z-
dc.date.issued1967-11-30ja
dc.identifier.issn0034-6675ja
dc.identifier.urihttp://hdl.handle.net/2433/46893-
dc.description.abstractThe kinetics of the gas-phase butadiene+2HI=buttne+I_2 has been studied from 180° to 230℃ using a photometric procedure. It is shown that the reaction mechanisms of the addition reaction of HI to butadiene consist of the following two steps. C_4H_6+HI→^^kC_4H_7I (slow), C_4H_7I+HI→C_4H_8+I_2 (fast). The second-order rate constant k is given by (units of l/mole-sec), log k=8.59-18.3/4.575T. The small activation energy of the addition reaction predicts that the -CH=CH_2 of butadiene exerts very interesting influence on the addition reaction rate.ja
dc.language.isoengja
dc.publisherThe Physico-Chemical Society of Japanja
dc.titleStudies on the kinetics of the gas-phase addition reaction of HI to butadiene Ija
dc.type.niitypeDepartmental Bulletin Paperja
dc.identifier.ncidAA00817661ja
dc.identifier.jtitleThe Review of Physical Chemistry of Japanja
dc.identifier.volume37ja
dc.identifier.issue1ja
dc.identifier.spage25ja
dc.identifier.epage31ja
dc.textversionpublisherja
dc.sortkey005ja
Appears in Collections:Vol.37 No.1

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