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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| rpcjpnv37p025.pdf | 1.08 MB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Kubota, Hironobu | en |
| dc.contributor.alternative | クボタ, ヒロノブ | ja |
| dc.contributor.transcription | クボタ, ヒロノブ | ja-Kana |
| dc.date.accessioned | 2007-09-10T06:45:33Z | - |
| dc.date.available | 2007-09-10T06:45:33Z | - |
| dc.date.issued | 1967-11-30 | - |
| dc.identifier.issn | 0034-6675 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/46893 | - |
| dc.description.abstract | The kinetics of the gas-phase butadiene+2HI=buttne+I_2 has been studied from 180° to 230℃ using a photometric procedure. It is shown that the reaction mechanisms of the addition reaction of HI to butadiene consist of the following two steps. C_4H_6+HI→^^kC_4H_7I (slow), C_4H_7I+HI→C_4H_8+I_2 (fast). The second-order rate constant k is given by (units of l/mole-sec), log k=8.59-18.3/4.575T. The small activation energy of the addition reaction predicts that the -CH=CH_2 of butadiene exerts very interesting influence on the addition reaction rate. | en |
| dc.language.iso | eng | - |
| dc.publisher | The Physico-Chemical Society of Japan | en |
| dc.title | Studies on the kinetics of the gas-phase addition reaction of HI to butadiene I | en |
| dc.type | departmental bulletin paper | - |
| dc.type.niitype | Departmental Bulletin Paper | - |
| dc.identifier.ncid | AA00817661 | - |
| dc.identifier.jtitle | The Review of Physical Chemistry of Japan | en |
| dc.identifier.volume | 37 | - |
| dc.identifier.issue | 1 | - |
| dc.identifier.spage | 25 | - |
| dc.identifier.epage | 31 | - |
| dc.textversion | publisher | - |
| dc.sortkey | 005 | - |
| dcterms.accessRights | open access | - |
| dc.identifier.pissn | 0034-6675 | - |
| 出現コレクション: | Vol.37 No.1 | |
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