Vapor-liquid equilibria in the systems : CO2-CO, CO2-CO-H2 and CO2-CH4 (The co-operative researches on the fundamental studies of the liquid phase reactions at high pressures)

Abstract

Vapor-liquid equilibria of the CO_2-CO, CO_2-CO-H_2 and CO_2-CH_4 systems were measured by the static method at -40 to 10℃. Also, for the CO_2-CH_4 system, orthobaric densities at dew and bubble points were determined by using a glass capillary tube at 10 and 20℃. And the P-V-T relations of homogeneous gas and liquid phases were also measured up to 200atm.