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dc.contributor.authorMitani, Tomomasaen
dc.contributor.authorOgo, Yoshiakien
dc.contributor.authorImoto, Tatsuyaen
dc.contributor.alternativeミタニ, トモマサja
dc.contributor.alternativeオゴウ, ヨシアキja
dc.contributor.alternativeイモト, タツヤja
dc.contributor.transcriptionミタニ, トモマサja-Kana
dc.contributor.transcriptionオゴウ, ヨシアキja-Kana
dc.contributor.transcriptionイモト, タツヤja-Kana
dc.date.accessioned2007-09-10T06:47:08Z-
dc.date.available2007-09-10T06:47:08Z-
dc.date.issued1972-09-30-
dc.identifier.issn0034-6675-
dc.identifier.urihttp://hdl.handle.net/2433/46967-
dc.description.abstractThe pressure effect on the kinetics of α-methylstyrene polymerization up to 5, 000kg/cm^2 and at various temperatures has been investigated. This polymerization system is characterized by the ceiling temperature, above which the formation of high polymer will not occur. The ratio of the rate constant of the propagation to that of the depropagation and the differences of activation parameters between them were calculated and discussed from the rate and thermodynamic equation derived by using the polymerization scheme with an accompanying depolymerization. The molecular weight of the polymer increased with pressure and the polymerization mechanism strongly depends on the nature of solvent.en
dc.language.isoeng-
dc.publisherThe Physico-Chemical Society of Japanen
dc.titleHigh pressure polymerization of α-methylstyreneen
dc.typedepartmental bulletin paper-
dc.type.niitypeDepartmental Bulletin Paper-
dc.identifier.ncidAA00817661-
dc.identifier.jtitleThe Review of Physical Chemistry of Japanen
dc.identifier.volume42-
dc.identifier.issue1-
dc.identifier.spage25-
dc.identifier.epage33-
dc.textversionpublisher-
dc.sortkey004-
dcterms.accessRightsopen access-
dc.identifier.pissn0034-6675-
出現コレクション:Vol.42 No.1

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