Access count of this item: 159
|Title:||Atropisomeric Flavoenzyme Models with a Modified Pyrimidine Ring (BIOORGANIC CHEMISTRY-Bioorganic Reaction Theory)|
(net) hydride transfer
|Publisher:||Institute for Chemical Research, Kyoto University|
|Journal title:||ICR annual report|
|Abstract:||Optically active 5-deazaflavin derivatives (3-aryl-10-(4-tert-butylphenyl)pyrimido[4,5-b]quinoline- 2,4(3H,10H)-dione) with an axial chirality at the pyrimidine ring have been synthesized, and the physical properties of these compounds have been investigated. In addition, (net) hydride-transfer reactions with NAD(P)H analogs have been carried out to elucidate the stereochemistry at the transition state of the reactions.|
|Appears in Collections:||Vol.3 (1996)|
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