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Title: Atropisomeric Flavoenzyme Models with a Modified Pyrimidine Ring (BIOORGANIC CHEMISTRY-Bioorganic Reaction Theory)
Authors: Ohno, Atsuyoshi
Kunitomo, Jun
Kawai, Yasushi
Keywords: flavin
axial chirality
NAD(P)H analog
(net) hydride transfer
stereochemistry
Issue Date: Mar-1997
Publisher: Institute for Chemical Research, Kyoto University
Journal title: ICR annual report
Volume: 3
Start page: 38
End page: 39
Abstract: Optically active 5-deazaflavin derivatives (3-aryl-10-(4-tert-butylphenyl)pyrimido[4,5-b]quinoline- 2,4(3H,10H)-dione) with an axial chirality at the pyrimidine ring have been synthesized, and the physical properties of these compounds have been investigated. In addition, (net) hydride-transfer reactions with NAD(P)H analogs have been carried out to elucidate the stereochemistry at the transition state of the reactions.
URI: http://hdl.handle.net/2433/65107
Appears in Collections:Vol.3 (1996)

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