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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| v6-p38.pdf | 67.5 kB | Adobe PDF | 見る/開く |
| タイトル: | Stereoselection Controlled by Electronic Effect of a Carbonyl Group in Oxidation of NAD(P)H Model (BIOORGANIC CHEMISTRY-Bioorganic Reaction Theory) |
| 著者: | Oda, Seiji Yamazaki, Norimasa |
| キーワード: | NAD(P)H model compound (net) hydride transfer stereochemistry carbonyl dipole oxidation |
| 発行日: | Mar-2000 |
| 出版者: | Institute for Chemical Research, Kyoto University |
| 誌名: | ICR Annual Report |
| 巻: | 6 |
| 開始ページ: | 38 |
| 終了ページ: | 39 |
| 抄録: | Newly synthesized NAD(P)H model compound (1, 4, 6, 7-tetrahydro-1, 6, 11-trimethyl-5-oxo-5Hbenzo[ c]pyrido[2, 3-e]azepin; 11Me-MMPAH) has an axial chirality with respect to carbonyl dipole in the side chain amide group. The orientation of carbonyl dipole is fixed with sticking out of the dihydropyridine ring. In oxidation of this compound with a series of p-benzoquinone derivatives, we investigated the relationship between the orientation of carbonyl dipole in nicotinamide and the stereochemistry of the reactions of NAD(P)H |
| URI: | http://hdl.handle.net/2433/65230 |
| 出現コレクション: | Vol.6 (1999) |
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