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v6-p06.pdf | 2.16 MB | Adobe PDF | 見る/開く |
タイトル: | TEM Analysis of Pt-particles Embedded on TiO2 Exhibiting High Photocatalytic Activity (STATES NAD STRUCTURES-Crystal Information Analysis) |
著者: | Tsujimoto, Masahiko Moriguchi, Sakumi Isoda, Seiji Kobayashi, Takashi Komatsu, Teruo |
キーワード: | Decomposing organic-platinum colloid Epitaxial growth Analytical electron microscopy |
発行日: | Mar-2000 |
出版者: | Institute for Chemical Research, Kyoto University |
誌名: | ICR Annual Report |
巻: | 6 |
開始ページ: | 6 |
終了ページ: | 7 |
抄録: | For fine particles of semiconductive rutile TiO2 supporting ultra-fine particles of Pt which were prepared by decomposing a colloidal organic-Pt complex, the structural aspects of the high photoactivity were examined by high resolution imaging, X-ray mapping by energy dispersive spectroscopy and electron energy-loss spectroscopy. As a result, the Pt particles with nm-sizes were found to grow epitaxially on rutile, which supports an expected mechanism that the photo-excited electrons efficiently transfer from TiO2 to Pt and promote the reduction of O2 to O2 -. |
URI: | http://hdl.handle.net/2433/65247 |
出現コレクション: | Vol.6 (1999) |

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