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dc.contributor.author | Bureekaew, Sareeya | en |
dc.contributor.author | Horike, Satoshi | en |
dc.contributor.author | Higuchi, Masakazu | en |
dc.contributor.author | Mizuno, Motohiro | en |
dc.contributor.author | Kawamura, Takashi | en |
dc.contributor.author | Tanaka, Daisuke | en |
dc.contributor.author | Yanai, Nobuhiro | en |
dc.contributor.author | Kitagawa, Susumu | en |
dc.contributor.alternative | 北川, 進 | ja |
dc.contributor.alternative | 堀毛, 悟史 | ja |
dc.date.accessioned | 2009-10-19T04:56:14Z | - |
dc.date.available | 2009-10-19T04:56:14Z | - |
dc.date.issued | 2009-10 | - |
dc.identifier.issn | 1476-1122 | - |
dc.identifier.uri | http://hdl.handle.net/2433/85349 | - |
dc.description | ナノ細孔の中で有機分子がプロトンを受け渡す -湿度ゼロ環境、100度以上で高いプロトン伝導性を示す 多孔性固体電解質の合成に成功-. 京都大学プレスリリース. 2009-09-07. | ja |
dc.description.abstract | The development of anhydrous proton-conductive materials operating at temperatures above 80 °C is a challenge that needs to be met for practical applications. Herein, we propose the new idea of encapsulation of a proton-carrier molecule—imidazole in this work—in aluminium porous coordination polymers for the creation of a hybridized proton conductor under anhydrous conditions. Tuning of the host–guest interaction can generate a good proton-conducting path at temperatures above 100 °C. The dynamics of the adsorbed imidazole strongly affect the conductivity determined by 2H solid-state NMR. Isotope measurements of conductivity using imidazole-d4 showed that the proton-hopping mechanism was dominant for the conducting path. This work suggests that the combination of guest molecules and a variety of microporous frameworks would afford highly mobile proton carriers in solids and gives an idea for designing a new type of proton conductor, particularly for high-temperature and anhydrous conditions. | en |
dc.language.iso | eng | - |
dc.publisher | Nature Publishing Group | en |
dc.rights | c 2009 Nature Publishing Group All Rights Reserved. 許諾条件により本文は2010-03-06に公開. | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.subject | porous coordination polymer | en |
dc.subject | metal−organic framework | en |
dc.subject | proton conductivity | en |
dc.subject | solid−state NMR | en |
dc.title | One-dimensional imidazole aggregate in aluminium porous coordination polymers with high proton conductivity | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Nature Materials | en |
dc.identifier.volume | 8 | - |
dc.identifier.spage | 831 | - |
dc.identifier.epage | 836 | - |
dc.relation.doi | 10.1038/nmat2526 | - |
dc.textversion | author | - |
dc.startdate.bitstreamsavailable | 2010-03-06 | - |
dc.identifier.pmid | 19734885 | - |
dc.relation.url | https://www.kyoto-u.ac.jp/static/ja/news_data/h/h1/news6/2009/090907_1.htm | - |
dcterms.accessRights | open access | - |
dc.identifier.pissn | 1476-1122 | - |
dc.identifier.eissn | 1476-4660 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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