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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| poc.3344.pdf | 1.25 MB | Adobe PDF | 見る/開く |
| タイトル: | Syntheses and structures of a stable gallole free of Lewis base coordination and its dianion |
| 著者: | Agou, Tomohiro Wasano, Tatsuya Sasamori, Takahiro Tokitoh, Norihiro    https://orcid.org/0000-0003-1083-7245 (unconfirmed) |
| 著者名の別形: | 吾郷, 友宏 時任, 宣博 |
| キーワード: | heteroles of heavier group 13 elements gallole gallole dianions X-ray crystallographic analysis |
| 発行日: | 9-Sep-2014 |
| 出版者: | wiley |
| 誌名: | Journal of Physical Organic Chemistry |
| 巻: | 28 |
| 号: | 2 |
| 開始ページ: | 104 |
| 終了ページ: | 107 |
| 抄録: | A stable Lewis base-free gallole bearing a bulky Mes[*] group (=2, 4, 6-(t-Bu)[3]C[6]H[2]) was synthesized by the treatment of Mes[*]GaCl[2] with a 3, 6-dilithio-3, 5-octadiene derivative. Reduction of the gallole with lithium metal afforded the corresponding gallole dianion species as a lithium salt. Structures of the gallole and the lithium salt of the gallole dianion have been elucidated by using X-ray crystallographic analysis, NMR spectroscopies, and density functional theory calculations |
| 著作権等: | This is the peer reviewed version of the following article: Agou T., Wasano T., Sasamori T. and Tokitoh N., (2015), Syntheses and structures of a stable gallole free of Lewis base coordination and its dianion, J. Phys. Org. Chem., 28, 104–107, which has been published in final form at http://dx.doi.org/10.1002/poc.3344. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. 許諾条件により本文ファイルは2015-09-09に公開. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/198687 |
| DOI(出版社版): | 10.1002/poc.3344 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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