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タイトル: | Electrochemical Properties of the Ionic Liquid 1-Ethyl-3-methylimidazolium Difluorophosphate as an Electrolyte for Electric Double-Layer Capacitors |
著者: | Matsumoto, Kazuhiko https://orcid.org/0000-0002-0770-9210 (unconfirmed) Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed) |
著者名の別形: | 松本, 一彦 |
発行日: | 6-Apr-2010 |
出版者: | The Electrochemical Society |
誌名: | Journal of The Electrochemical Society |
巻: | 157 |
号: | 5 |
開始ページ: | A578 |
終了ページ: | A581 |
抄録: | The electrochemical properties of 1-ethyl-3-methylimidazolium difluorophosphate (EMImPO2F2) ionic liquid have been investigated as an electrolyte for electric double-layer capacitors using activated carbon electrodes. A two-electrode cell test reveals that the capacitance of EMImPO2F2 exhibits a larger voltage dependence than that of a typical ionic liquid electrolyte EMImBF4. At a charging voltage of 2.5 V, the capacitance obtained for EMImPO2F2 is 49 F g−1 and is larger than 44 F g−1 obtained for EMImBF4. According to the charge–discharge cycle test, the breaking-up voltage of EMImPO2F2 is lower than that of EMImBF4, which may be caused by the lower anodic stability of PO2F2− than that of BF4−. The ionization potential of PO2F2− was calculated by quantum mechanical calculations to estimate its anodic stability and was compared with those of several anions used in typical electrolytes. The results indicate that the anodic stability of PO2F2- is similar to that of ClO4− and lower than those of BF4- and PF6-. |
著作権等: | ©2010 The Electrochemical Society |
URI: | http://hdl.handle.net/2433/128849 |
DOI(出版社版): | 10.1149/1.3336831 |
出現コレクション: | 学術雑誌掲載論文等 |
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