Hull cell tests for evaluating the effects of polyethylene amines as brighteners in the electrodeposition of aluminum from dimethylsulfone-AlCl3 baths

Abstract

Hull cell tests were carried out to examine a series of polyethylene amines to evaluate their abilities as brighteners in the electrodeposition of aluminum from a dimethylsulfone (DMSO2)-AlCl3 bath. The tests demonstrated the current density ranges that yielded bright, semi-bright, dull, burnt, and streaked Al deposits from the baths containing each polyethylene amine at a variety of concentrations. Among the amines examined in this study, triethylenetetramine (TETA) was found to be the most effective brightener, providing a bright Al deposit with the highest specular reflectance over a wide range of current densities. No correlation was found between the preferential crystal orientation of the Al and the brightness of the deposit, which along with the acquired scanning electron microscopy images, indicated that surface morphology was primarily responsible for the differences in brightness.