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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| 2.0401501jes.pdf | 2.45 MB | Adobe PDF | 見る/開く |
| タイトル: | Oxidation of Nickel in AlCl3-1-Butylpyridinium Chloride at Ambient Temperature |
| 著者: | Nakaya, K. Nakata, A. Hirai, T. Ogumi, Z. |
| 著者名の別形: | 平井, 敏郎 |
| 発行日: | 13-Nov-2014 |
| 出版者: | Electrochemical Society |
| 誌名: | Journal of the Electrochemical Society |
| 巻: | 162 |
| 号: | 1 |
| 開始ページ: | D42 |
| 終了ページ: | D48 |
| 抄録: | We have studied in detail the electrochemical reaction of nickel in several kinds of molar ratio-controlled molten salts consisting of AlCl(3) and 1-butylpyridinium chloride (BPC) at 40°C. We observed NiCl(2) as an oxidation product from nickel on the surface of the electrode in slightly acidic AlCl(3)/BPC salts with molar ratios of 1.05/1.0 and 1.1/1.0. However, in strongly acidic salt with the ratio of 1.5/1.0, NiCl(2) deposits on the electrode less than when in the above salts, and no NiCl(29) is observed in basic and neutral salts with the ratio of 1.0/1.0 or less AlCl(3) content. This suggests that [NiCl(4)](2−) ions form as the oxidation of nickel in such neutral and basic AlC(3)/BPC (salts). |
| 著作権等: | © The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. |
| URI: | http://hdl.handle.net/2433/196780 |
| DOI(出版社版): | 10.1149/2.0401501jes |
| 出現コレクション: | 学術雑誌掲載論文等 |
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