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dc.contributor.author | Kuroda, Yusuke | en |
dc.contributor.author | Harada, Shingo | en |
dc.contributor.author | Oonishi, Akinori | en |
dc.contributor.author | Yamaoka, Yousuke | en |
dc.contributor.author | Yamada, Ken-Ichi | en |
dc.contributor.author | Takasu, Kiyosei | en |
dc.contributor.alternative | 山田, 健一 | ja |
dc.date.accessioned | 2015-11-13T02:48:34Z | - |
dc.date.available | 2015-11-13T02:48:34Z | - |
dc.date.issued | 2015-05-28 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2433/201549 | - |
dc.description.abstract | A Brønsted-acid-catalyzed intramolecular enantioselective S(N)2' reaction was developed utilizing trichloroacetimidate as a leaving group. The findings indicated that dual activation of the substrates is operative. This metal-free allylic alkylation allows highly enantioselective access to 2-vinylpyrrolidines bearing various substituents. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley | en |
dc.rights | This is the peer reviewed version of the following article: Kuroda, Y., Harada, S., Oonishi, A., Yamaoka, Y., Yamada, K.-i. and Takasu, K. (2015), Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S(N)2' Reaction. Angew. Chem. Int. Ed., 54: 8263–8266, which has been published in final form at http://dx.doi.org/10.1002/anie.201502831. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | en |
dc.rights | The full-text file will be made open to the public on 28 May 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.subject | asymmetric catalysis | en |
dc.subject | nucleophilic substitution | en |
dc.subject | organocatalysis | en |
dc.subject | pyrrolidines | en |
dc.title | Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S(N) 2' Reaction. | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.ncid | AA0052535X | - |
dc.identifier.jtitle | Angewandte Chemie | en |
dc.identifier.volume | 54 | - |
dc.identifier.issue | 28 | - |
dc.identifier.spage | 8263 | - |
dc.identifier.epage | 8266 | - |
dc.relation.doi | 10.1002/anie.201502831 | - |
dc.textversion | author | - |
dc.startdate.bitstreamsavailable | 2016-05-28 | - |
dc.identifier.pmid | 26016987 | - |
dcterms.accessRights | open access | - |
dc.identifier.pissn | 1433-7851 | - |
dc.identifier.eissn | 1521-3773 | - |
出現コレクション: | 学術雑誌掲載論文等 |
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