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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| anie.201502831.pdf | 982.96 kB | Adobe PDF | 見る/開く |
| タイトル: | Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S(N) 2' Reaction. |
| 著者: | Kuroda, Yusuke    https://orcid.org/0000-0003-0952-7098 (unconfirmed)Harada, Shingo Oonishi, Akinori Yamaoka, Yousuke Yamada, Ken-Ichi Takasu, Kiyosei https://orcid.org/0000-0002-1798-7919 (unconfirmed) |
| 著者名の別形: | 山田, 健一 |
| キーワード: | asymmetric catalysis nucleophilic substitution organocatalysis pyrrolidines |
| 発行日: | 28-May-2015 |
| 出版者: | Wiley |
| 誌名: | Angewandte Chemie |
| 巻: | 54 |
| 号: | 28 |
| 開始ページ: | 8263 |
| 終了ページ: | 8266 |
| 抄録: | A Brønsted-acid-catalyzed intramolecular enantioselective S(N)2' reaction was developed utilizing trichloroacetimidate as a leaving group. The findings indicated that dual activation of the substrates is operative. This metal-free allylic alkylation allows highly enantioselective access to 2-vinylpyrrolidines bearing various substituents. |
| 著作権等: | This is the peer reviewed version of the following article: Kuroda, Y., Harada, S., Oonishi, A., Yamaoka, Y., Yamada, K.-i. and Takasu, K. (2015), Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric S(N)2' Reaction. Angew. Chem. Int. Ed., 54: 8263–8266, which has been published in final form at http://dx.doi.org/10.1002/anie.201502831. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. The full-text file will be made open to the public on 28 May 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
| URI: | http://hdl.handle.net/2433/201549 |
| DOI(出版社版): | 10.1002/anie.201502831 |
| PubMed ID: | 26016987 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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