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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| sciadv.1603224.pdf | 381 kB | Adobe PDF | 見る/開く |
完全メタデータレコード
| DCフィールド | 値 | 言語 |
|---|---|---|
| dc.contributor.author | Luckhaus, David | en |
| dc.contributor.author | Yamamoto, Yo-ichi | en |
| dc.contributor.author | Suzuki, Toshinori | en |
| dc.contributor.author | Signorell, Ruth | en |
| dc.contributor.alternative | 山本, 遙一 | ja |
| dc.contributor.alternative | 鈴木, 俊法 | ja |
| dc.date.accessioned | 2017-05-01T05:50:52Z | - |
| dc.date.available | 2017-05-01T05:50:52Z | - |
| dc.date.issued | 2017-04-28 | - |
| dc.identifier.issn | 2375-2548 | - |
| dc.identifier.uri | http://hdl.handle.net/2433/224806 | - |
| dc.description | 水の中で安定化した電子のエネルギーを決定 . 京都大学プレスリリース. 2017-05-01. | ja |
| dc.description.abstract | The unknown influence of inelastic and elastic scattering of slow electrons in water has made it difficult to clarify the role of the solvated electron in radiation chemistry and biology. We combine accurate scattering simulations with experimental photoemission spectroscopy of the hydrated electron in a liquid water microjet, with the aim of resolving ambiguities regarding the influence of electron scattering on binding energy spectra, photoelectron angular distributions, and probing depths. The scattering parameters used in the simulations are retrieved from independent photoemission experiments of water droplets. For the ground-state hydrated electron, we report genuine values devoid of scattering contributions for the vertical binding energy and the anisotropy parameter of 3.7 ± 0.1 eV and 0.6 ± 0.2, respectively. Our probing depths suggest that even vacuum ultraviolet probing is not particularly surface-selective. Our work demonstrates the importance of quantitative scattering simulations for a detailed analysis of key properties of the hydrated electron. | en |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | American Association for the Advancement of Science (AAAS) | en |
| dc.rights | © 2017, The Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited. | en |
| dc.subject | solvated electron | en |
| dc.subject | electron scattering | en |
| dc.subject | liquid water | en |
| dc.subject | photoelectron spectroscopy | en |
| dc.subject | radiation chemistry | en |
| dc.title | Genuine binding energy of the hydrated electron | en |
| dc.type | journal article | - |
| dc.type.niitype | Journal Article | - |
| dc.identifier.jtitle | Science Advances | en |
| dc.identifier.volume | 3 | - |
| dc.identifier.issue | 4 | - |
| dc.relation.doi | 10.1126/sciadv.1603224 | - |
| dc.textversion | publisher | - |
| dc.identifier.artnum | e1603224 | - |
| dc.identifier.pmid | 28508051 | - |
| dc.relation.url | https://www.kyoto-u.ac.jp/ja/research-news/2017-05-01 | - |
| dcterms.accessRights | open access | - |
| 出現コレクション: | 学術雑誌掲載論文等 | |
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