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| ファイル | 記述 | サイズ | フォーマット | |
|---|---|---|---|---|
| molecules24030642.pdf | 2.3 MB | Adobe PDF | 見る/開く |
| タイトル: | Synthesis of Meso-Diarylaminocorroles via SNAr Reactions |
| 著者: | Ueta, Kento Tanaka, Takayuki    https://orcid.org/0000-0001-8018-7984 (unconfirmed)Osuka, Atsuhiro |
| 著者名の別形: | 植田, 賢人 田中, 隆行 大須賀, 篤弘 |
| キーワード: | corrole peripheral substitution SNAr reaction UV/Vis absorption cyclic voltammetry |
| 発行日: | 1-Feb-2019 |
| 出版者: | MDPI AG |
| 誌名: | Molecules |
| 巻: | 24 |
| 号: | 3 |
| 論文番号: | 642 |
| 抄録: | A corrole is a tetrapyrrolic macrocycle known as a ring-contracted porphyrinoid. Despite the progress of the synthetic chemistry of meso-aryl-substituted corroles since the early 2000s, meso-heteroatom-substituted corroles have been scarcely reported. Herein we report that the SNAr-type substitution reaction of a meso-chlorocorrole silver complex with diphenylamine or carbazole in the presence of NaH as a base produced meso-aminocorroles. The structures, ultraviolet–visible spectroscopy (UV/Vis), and emission spectra of these meso-aminocorroles were discussed. Furthermore, the oxidation reaction of a meso-diphenylaminocorrole was examined, which resulted in the formation of 10, 10-diethoxyisocorrole. |
| 著作権等: | © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| URI: | http://hdl.handle.net/2433/236665 |
| DOI(出版社版): | 10.3390/molecules24030642 |
| PubMed ID: | 30759763 |
| 出現コレクション: | 学術雑誌掲載論文等 |
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