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dc.contributor.authorHakamada, Masatakaen
dc.contributor.authorSato, Yutoen
dc.contributor.authorMabuchi, Mamoruen
dc.contributor.alternative袴田, 昌高ja
dc.contributor.alternative佐藤, 優斗ja
dc.contributor.alternative馬渕, 守ja
dc.date.accessioned2019-03-27T06:40:00Z-
dc.date.available2019-03-27T06:40:00Z-
dc.date.issued2019-03-
dc.identifier.issn2159-6859-
dc.identifier.urihttp://hdl.handle.net/2433/237616-
dc.description.abstractBimodal nanoporous platinum (BNP-Pt) is synthesized by using a sacrificial nanoporous copper (NP-Cu) support for oxygen-reduction-reaction (ORR) catalysts in fuel cells. The specific ORR catalytic activity of BNP-Pt increases by the dissolution and removal of supporting NP-Cu, suggesting that the BNP structure improves the intrinsic catalytic properties of platinum. The lattice contraction of BNP-Pt containing residual copper even after NP-Cu removal is milder than predicted by Vegard's law. The BNP structure governs the intrinsic catalytic activity of the platinum by relaxing the lattice contraction and by alloying with copper and/or misfit strain at the Pt/Cu interface.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherCambridge University Press (CUP)en
dc.rightsThis article has been published in a revised form in 'MRS Communications', https://doi.org/10.1557/mrc.2018.223. This version is free to view and download for private research and study only. Not for re-distribution, re-sale or use in derivative works. © Materials Research Society.en
dc.rightsThe full-text file will be made open to the public on 1 September 2019 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.rightsこの論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。ja
dc.rightsThis is not the published version. Please cite only the published version.en
dc.titleBimodal nanoporous platinum on sacrificial nanoporous copper for catalysis of the oxygen-reduction reactionen
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleMRS Communicationsen
dc.identifier.volume9-
dc.identifier.issue1-
dc.identifier.spage292-
dc.identifier.epage297-
dc.relation.doi10.1557/mrc.2018.223-
dc.textversionauthor-
dc.addressDepartment of Energy Science and Technology, Graduate School of Energy Science, Kyoto Universityen
dc.addressDepartment of Energy Science and Technology, Graduate School of Energy Science, Kyoto Universityen
dc.addressDepartment of Energy Science and Technology, Graduate School of Energy Science, Kyoto Universityen
dc.startdate.bitstreamsavailable2019-09-01-
dcterms.accessRightsopen access-
datacite.date.available2019-09-01-
dc.identifier.eissn2159-6867-
出現コレクション:学術雑誌掲載論文等

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