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DCフィールド | 値 | 言語 |
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dc.contributor.author | Endo, Atsushi | en |
dc.contributor.author | Miyake, Masao | en |
dc.contributor.author | Hirato, Tetsuji | en |
dc.contributor.alternative | 遠藤, 厚志 | ja |
dc.contributor.alternative | 三宅, 正男 | ja |
dc.contributor.alternative | 平藤, 哲司 | ja |
dc.date.accessioned | 2019-03-27T06:40:04Z | - |
dc.date.available | 2019-03-27T06:40:04Z | - |
dc.date.issued | 2014-08-10 | - |
dc.identifier.issn | 0013-4686 | - |
dc.identifier.uri | http://hdl.handle.net/2433/237635 | - |
dc.description.abstract | This study investigated the use of novel organic solvent baths for the electrodeposition of aluminum at near-ambient temperatures. It was found that Al metal can be electrodeposited from baths that were composed of 1, 3-dimethyl-2-imidazolidinone (DMI) and AlCl₃, with an AlCl₃ concentration greater than 50 mol%. IR spectroscopy indicated that Al₂Cl₇⁻ions were present in the baths that contained >50 mol% AlCl₃, where the electrodeposition of Al occurs from Al₂Cl₇⁻ion. The DMI/AlCl₃ baths with AlCl₃ concentrations between 59 and 64 mol% retained a single liquid phase without precipitation at 25 ℃, and therefore, they can be used for Al electrodeposition near room temperature. Smooth Al films could be obtained by galvanostatic electrodeposition at 40 ℃ using a DMI/AlCl₃ bath with the addition of a trace amount of 1, 10-phenanthroline. | en |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd. | en |
dc.rights | © 2014. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. | en |
dc.rights | The full-text file will be made open to the public on 10 August 2016 in accordance with publisher's 'Terms and Conditions for Self-Archiving' | en |
dc.rights | この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 | ja |
dc.rights | This is not the published version. Please cite only the published version. | en |
dc.subject | Electroplating | en |
dc.subject | Electrodeposition | en |
dc.subject | Organic solvent bath | en |
dc.title | Electrodeposition of Aluminum from 1,3-Dimethyl-2-Imidazolidinone/AlCl₃ baths | en |
dc.type | journal article | - |
dc.type.niitype | Journal Article | - |
dc.identifier.jtitle | Electrochimica Acta | en |
dc.identifier.volume | 137 | - |
dc.identifier.spage | 470 | - |
dc.identifier.epage | 475 | - |
dc.relation.doi | 10.1016/j.electacta.2014.06.044 | - |
dc.textversion | author | - |
dc.address | Graduate School of Energy Science, Kyoto University | en |
dc.address | Graduate School of Energy Science, Kyoto University | en |
dc.address | Graduate School of Energy Science, Kyoto University | en |
dc.startdate.bitstreamsavailable | 2016-08-10 | - |
dcterms.accessRights | open access | - |
datacite.date.available | 2016-08-10 | - |
datacite.awardNumber | 24360308 | - |
jpcoar.funderName | 日本学術振興会 | ja |
jpcoar.funderName.alternative | Japan Society for the Promotion of Science (JSPS) | en |
出現コレクション: | 学術雑誌掲載論文等 |
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