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dc.contributor.authorWatanabe, Toshihiroen
dc.contributor.authorKawamoto, Haruoen
dc.contributor.authorSaka, Shiroen
dc.contributor.alternative渡辺, 敏弘ja
dc.contributor.alternative河本, 晴雄ja
dc.contributor.alternative坂, 志朗ja
dc.date.accessioned2019-04-04T05:52:35Z-
dc.date.available2019-04-04T05:52:35Z-
dc.date.issued2009-07-01-
dc.identifier.issn0018-3830-
dc.identifier.issn1437-434X-
dc.identifier.urihttp://hdl.handle.net/2433/240652-
dc.description.abstractβ-Ether-type dimers, [1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-1-propanol and 1-(3, 4-dimethoxyphenyl)-2-(2-methoxyphenoxy)-1-propanol], and an α, β-diether-type trimer [1-(4-(3, 4-dimethoxybenzyloxy)-3-methoxyphenyl) -2- (2-methoxyphenoxy) -1-propanol] were pyrolyzed in a closed ampoule reactor (N₂/250–400°C/2 min). 1-Phenylpropenes (Cα=Cβ) and 1-phenylpropanones (Cα=O) were obtained as the major β-ether-cleaved products. Radical chain mechanisms are proposed in which hydrogen abstraction at the phenolic O-H and Cα-Hs occurs, respectively. The former reaction which gives rise to three radical species was much more effective than the latter. As the effective reaction increases the radical concentration, cleavage of the β-ether linkage in the phenolic dimer is achieved at a much lower temperature (260°C) than that of the non-phenolic type (360°C). Radical chain reactions are initiated in the case of the trimer with a weak Cα-O bond at lower temperature (320°C) than those of the non-phenolic (methylated) dimer, since homolysis of the Cα-O bond produces the phenoxy type dimer and 3, 4-dimethoxybenzyl radicals as initiators. However, some of the dimer phenoxyl radical was stabilized by H-abstraction (to form dimer) or by recombination with a 3, 4-dimethoxybenzyl radical (to form C-benzylated products) so that the chain depolymerization via quinone methide intermediate was suppressed.en
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherDe Gruyteren
dc.rights© by Walter de Gruyter • Berlin • New York.en
dc.rightsThe full-text file will be made open to the public on 1 July 2010 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.en
dc.subjectα-etheren
dc.subjectβ-etheren
dc.subjecthydrogen abstractionen
dc.subjectligninen
dc.subjectpyrolysisen
dc.subjectradical chain reactionen
dc.titleRadical chain reactions in pyrolytic cleavage of the ether linkages of lignin model dimers and a trimeren
dc.typejournal article-
dc.type.niitypeJournal Article-
dc.identifier.jtitleHolzforschungen
dc.identifier.volume63-
dc.identifier.issue4-
dc.identifier.spage424-
dc.identifier.epage430-
dc.relation.doi10.1515/HF.2009.076-
dc.textversionpublisher-
dc.addressGraduate School of Energy Science, Kyoto Universityen
dc.addressGraduate School of Energy Science, Kyoto Universityen
dc.addressGraduate School of Energy Science, Kyoto Universityen
dcterms.accessRightsopen access-
datacite.date.available2010-07-01-
datacite.awardNumber18580163-
jpcoar.funderName日本学術振興会ja
jpcoar.funderName.alternativeJapan Society for the Promotion of Science (JSPS)en
出現コレクション:学術雑誌掲載論文等

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